Industry 5.0 is a new way of thinking that is consistent with the ideas of Industry 4.0 but places greater emphasis on sustainability, sustainability, and human-centricity. Unlike Industry 4.0, which emphasizes the efficient integration of advanced technologies such as the Internet, AI, robots, and automation, Industry 5.0 seeks to balance human-machine collaboration to create more inclusive, meaningful, and sustainable systems. In Industry 5.0, LLM has a bigger role than automating similar activities. LLMs make sectors more resilient, adaptable and aligned with social values by fostering innovation, improving human-centred processes and promoting sustainable practices. Industry 5.0 will create a revolutionary force in the global industrial landscape thanks to a combination of emerging technologies that will further enhance the synergies between human creativity and machine intelligence.