Phanerozoic orogenic gold mineralization at craton margins is related to the metasomatism of the lithospheric mantle by crustal material. Slab subduction transfers Au from the crust to the metasomatized mantle and oxidizes the latter to facilitate the mobilization of Au into mantle melts. The role of volatiles in the mobilization of Au in the mantle is unclear because of the absence of direct geochemical evidence relating the mantle source of Au to Au mineralization in the overlying crust. This study uses lithium isotopes from a large suite of lamprophyres to characterize the mantle beneath the eastern North China Craton, which hosts giant Mesozoic gold deposits. Our results indicate a strong genetic link between carbonate metasomatism in the mantle and Au mineralization in the overlying crust. Although pre-enrichment of Au in the mantle is critical for forming giant Au provinces, the oxidation of the lithospheric mantle controls the mobilization of Au.

Alkaline silicate intrusions host large rare-earth-element (REE) resources, yet the precise origin of the mantle enrichment that generates these magmas remains unresolved. Here, we use a combination of Li-Ba-Sr-Nd isotopic data to clarify the processes responsible for the metasomatic enrichment of the mantle source. We focus on alkaline complexes in the North China Craton that host giant REE deposits, which exhibit broadly similar Li-Ba-Sr-Nd isotopic signatures, despite forming in different tectonic settings. Neither recycling of altered oceanic crust nor serpentinite-related metasomatism can reproduce these coupled geochemical signatures; instead, they require the addition of subducted continent-derived sediment derived from weathered continental crust. Storage of these REE-rich sediments within the lithospheric mantle lowers its solidus and creates chemically fertile domains. Lithospheric extension subsequently triggers selective melting of these domains, generating REE-rich alkaline magmas. Our findings suggest that continent-derived sediment recycling plays an important role in shaping the critical-metal budget of the Earth.

The giant Husab uranium deposit is located in the Paleoproterozoic Abbabis Metamorphic Complex, which was highly partially melted and metamorphosed during the Damara Orogenic Event. The timing of magma emplacement has been investigated; however, the petrogenesis is unclear. Here we reported petrology, geochemistry, and monazite U-Pb age data from biotite granitic gneisses, syeno-granite, syeno-granitic pegmatites, syeno-granitic gneiss, granitic syenite and biotite quartz monzonites of this complex. Geochemical data suggest that these Paleoproterozoic rocks show high SiO₂, Al₂O₃, and K₂O, moderate Na₂O, low CaO and Fe₂O₃, and MgO abundance. The alkali-calcic to alkalic, peraluminous, low Fe-number, depletion in HFSE (Nb-Ta, Ti) and enrichment in LILE (e.g., Rb, Pb) characteristic correspond with I- and S-type granite. Major and trace elements are strongly fractionated with the increase of SiO₂, which, together with strongly fractionated LREE patterns and high (La/Yb)_N ratios of the biotite granitic gneiss and syeno-granitic gneiss, suggest that the magma was highly evolved and fractionated. Monazite U-Pb data show three metamorphic age groups of 581–535 Ma, 531–522 Ma and 518–484 Ma. The increasing trend of La/Sm and La/Yb with the increase of La, suggest these rocks most likely experienced a partial melting process during the late Palaeozoic metamorphism. We, thus, propose a fractional crystallization model for the generation of the Paleoproterozoic Abbabis Metamorphic Complex basement rock, which was metamorphosed and melted during the late Palaeozoic Damara Orogenic Event and provided the magma sources for primary uranium mineralization.

The closure time of the Shangdan Ocean is critical for understanding the tectonic evolution of the Proto-Tethys Ocean. However, the proposed closure time was prolonged from Ordovician to Devonian. In the present study, detrital zircon from the metasedimentary rocks of the Liba Group in the West Qinling Belt was analyzed to constrain the closure time of the Shangdan Ocean. The three youngest grains from the Liba Group yield a maximum deposition age of 418 ± 13 Ma, indicating the Middle Devonian deposition. Detrital zircon grains show two main U–Pb age peaks of 810 Ma and 440 Ma with εHf_(t) values spanning from −24.3 to +8.8 and −6.3 to +4.1, respectively, suggesting that the sediments of the Liba Group were derived from both the North and South Qinling Belts. The Lower Devonian in the South Qinling Belt shows similar provenance to the Liba Group, whereas sediments from the North Qinling Belt are absent in the Silurian strata of the South Qinling Belt. From Late Silurian to Early Devonian, the tectonic setting changed from subduction to collision. This evidence consistently suggests the disappearance of the Shangdan Ocean. The noticeable decrease in magmatism from 510–420 Ma to 420–390 Ma and the shrinking of εHf_(t) values from −15.5–+12.8 to −8.4–+4.2 reveal that the Shangdan Ocean, as the eastmost embranchment of the Proto-Tethys Ocean, was closed at ca. 420 Ma.

The Luxi Terrane (eastern China) exposes widespread Early Cretaceous alkaline rocks, whereas their petrogenesis remains controversial, including fractional crystallization, partial melting and crustal contamination regime. Here, we present petrology, geochemistry, sphene U-Pb geochronology and trace element data from the syenogranite, quartz syenite and quartz monzonite of the Guandimiao alkaline complex rocks to investigate their petrogenesis. Geochemical data suggest that these alkaline rocks show alkalic and peralkaline characters, and high Ga/Al ratios, SiO₂, light rare-earth element (LREE), Zr and Nb, and low MgO, CaO, Eu contents, corresponding to A-type granites. Sphene trace elements in syenogranite and quartz monzonite show obvious fractionation between LREE and heavy rare-earth element (HREE) and high Th/U ratios, indicating a magmatic origin. They yield U-Pb lower intercept ages of 128 ± 2.3 Ma and 127 ± 1.3 Ma, representing the crystallization ages of these alkaline rocks. The negative correlations between CaO, Fe₂O₃ (Total), MgO, P₂O₅, TiO₂, MnO and the pronounced depletion in Nb, Ta and Ti suggest that the alkaline rocks were formed by fractional crystallization. Additionally, the positive correlation between La/Hf and La, Th and Th/V, Ce/Yb and K₂O, and Tb/Yb and Yb suggest that the alkaline melts are generated by partial melting. Such high Rb/Nb, (Th/Nb)_N and Nb/Th ratios indicate crustal contamination during the magma emplacement. We, therefore, propose the magma source of the alkaline rocks in the Guandimiao complex originated by partial melting of lithospheric mantle, which experienced fractional crystallization and crustal contamination processes during its emplacement. Such complex alkaline rocks were probably formed in an extensional back-arc setting induced by the retreat of the subducting Izanagi plate.