In recent years, numerous studies have focused on the use of biochar as a biological material for environmental remediation due to its low-cost precursor (waste), low toxicity, and diversity of active sites, along with their facile tailoring techniques. Due to its versatility, biochar has been employed as an adsorbent, catalyst (for activating hydrogen peroxide, ozone, persulfate), and photocatalyst. This review aims to provide a comprehensive overview and compare the application of biochar in water remediation. First, the biochar active sites with their functions are presented. Secondly, an overview and summary of biochar performance in treating organic pollutants in different systems is depicted. Thereafter, an evaluation on performance, removal mechanism, active sites involvement, tolerance to different pH values, stability, and reusability, and an economic analysis of implementing biochar for organic pollutants decontamination in each application is presented. Finally, potential prospects to overcome the drawbacks of each application are provided.