There are abundant phosphate mines in the High Atlas Mountains of Morocco. Gem-quality apatite is produced at the Anemzi deposit, but its associated gem mineralogy is relatively poorly studied. In this study, apatite from the Anemzi mine in Morocco was analysed using standard gemmological characterisation methods, including basic tests (hardness, relative density, microscopy, etc.), spectroscopic tests (infrared, Raman, and ultraviolet–visible spectroscopy), and chemical analyses (electron probe and laser ablation inductively coupled plasma mass spectrometry). This paper explores the gemmological characteristics of Moroccan apatites and the information on diagenesis recorded for apatites by comparing them with apatites from other sources. Apatite from the Anemzi deposit is an igneous fluorapatite. The relatively high Cl content of the apatite suggests that the magma in the area has a high Cl content, whereas the high Cl/F ratio may indicate that the deposit formed in a slab subduction environment. The characteristics of the major and trace elements indicate high oxygen and sulphur escapes in the apatite-forming magma.
Madagascar is known as the ‘Island of Gemstones’ because it is full of gemstone resources. Apatite from Madagascar is widely popular because of its greenish blue Paraiba-like color. This study analyzes apatite from Madagascar through standard gemological characteristic methods, spectroscopic tests and chemical analyses (i.e., electron probe and laser ablation inductively coupled plasma mass spectrometry). This work explores the gemological and the diagenesis information recorded on Madagascar apatite by comparing them with apatite from other sources and establishes the origin information of Madagascar apatite. The origin characteristics are as follows: Apatite from Madagascar is fluorapatite, with excellent diaphaneity, greenish–blue color caused by Ce and Nd and crystal structure distortion indicated by spectroscopic tests. The F/Cl ratio (16.47 to 21.89) suggests its magmatic origin Cl loss during the weathering processes forming the source rocks, and lg fO2 (−10.30 to −10.35) reflects the high oxidation degree of magma.
The Mogok metamorphic belt (MMB) of Myanmar is a famous geographical origin acknowledged by the whole world for its large mineral resources. In this study, basic gemological tests (density, UV fluorescence, refractive index, etc.), spectroscopic tests (infrared spectrum, Raman spectrum, and ultra-violet visible spectrum) and chemical composition analysis (electron microprobe and laser ablation inductively coupled plasma mass spectrometer) were carried out on scapolites from Myanmar. This paper explores the mineralogical characteristics of Burmese scapolites and provides additional information on its origin. Burmese scapolites are colorless and transparent with a yellow tone and belong to Cl-rich dipyre. The infrared spectra of the samples show the vibrations of Si-O and Al-O (400–1300 cm−1), (CO3)2− (1400–300 cm−1), and OH (3048 cm−1 and 3568 cm−1). The Raman spectra are mainly the vibrational spectra of Si (Al)-O-Si (Al) and the absorption peaks at 992 cm−1 and 1110 cm−1 caused by the vibrations of sulfate and carbonate ions, respectively. Black inclusions were found inside the scapolites, and the dark inclusions were identified as graphite by Raman spectroscopy. Moreover, the composition of the scapolite could be influenced by the αCl−/α(CO3)2− of the fluid. The Cl activity degree could control the scapolite content as the ion exchange between scapolite and plagioclase was gradually balanced. The enrichment of rare earth elements and the apparent positive Eu anomaly indicate that Burmese scapolites have a high degree of light and heavy rare earth element differentiation and an oxidizing environment of mineralization.