To solve the problem of the global energy shortage and the pollution of the environment, in recent years, semiconductor photocatalytic technology that converts solar energy into chemical fuel has been widely studied. Regarding semiconductor-based photocatalysts, CdS has attracted extensive attention due to its relatively narrow bandgap for visible-light response and sufficiently negative potential of the conduction band edge for the reduction of protons. Studies have shown that CdS-based photocatalysts possess excellent photocatalytic performance in terms of solar-fuel generation and environmental purification. This critical review presents the recent advances and progress in the design and synthesis of various CdS and CdS-based photocatalysts. The basic physical and chemical properties of CdS and the related growth mechanism have been briefly summarized. Moreover, the applications of CdS-based photocatalysts have been discussed such as in photocatalytic hydrogen production, reduction of CO2 to hydrocarbon fuels and degradation of pollutants. Finally, a brief perspective on the challenges and future directions for the development of CdS and CdS-based photocatalysts are also presented.
This review focuses on the systematic understanding of recent advances in MXene and MXene-based photocatalysts. In particular, the defects and improvements of MXene and the design of MXene-based photocatalysts are uniquely classified and clarified.
Textile-based wearable devices have attracted increasing attention because of their softness, breathability, and biocompatibility, which makes them durable and wearable for long-term application. To date, the fabrication of multifunctional wearable electronic textiles (E-textiles) that integrate sensing and heating properties via an energy-saving method remains a great challenge. Herein, we have proposed a multifunctional integration strategy using integrated nanowire-coated fabrics that can deliver pressure sensing capabilities simultaneously with thermal insulation, Joule heating, and particulate matter (PM) filter features. The collective effect of the fiber/yarn/fabric multi-scale contacts produces a highly sensitive multifunctional E-textile, with a sensitivity of approximately 3.24 × 105 kPa−1 at 0–10 kPa and 2.16 × 104 kPa−1 at 10–100 kPa, respectively. Each layer contained a conductive network of metallic nanowires (NWs) that could reflect the infrared radiation (IR) emitted by the human body and synergistically enhance the thermal insulation property of the multifunctional E-textile, thus enabling a 5 °C decrease in the setpoint as compared to the normal cotton textile. In addition to passively insulating heat loss, the E-textile can also function as a wearable heater, inducing fast thermal response and uniform electroheating. Furthermore, it can act as a high-efficiency air filter for high-temperature PM2.5 particle removal. The outstanding integrated property is expected to be applicable in the fields of smart clothes, human monitoring and healthcare, air filtration, and lightweight body armor in extreme climate conditions.
MXene Ti3C2/TiO2 hybrids with a 2D multilayer structure, prepared by calcination of F-terminated Ti3C2, exhibited an enhanced photocatalytic H2-production activity.