Mixed matrix membranes (MMMs), possessing high porosity, have received extensive attention for gas sensing applications. However, those with high flexibility and significant sensitivity are rare. In this work, we report on the fabrication of a novel membrane, using Cu₃(HHTP)₂ MOF (Cu-MOF) embedded in a polymer matrix. A solution comprising a homogenous suspension of poly-vinyl alcohol (PVA) and ionic liquid (IL), and Cu-MOF solid particles, was cast onto a petri dish to obtain a flexible membrane (215 μm in thickness). The sensor membrane (Cu-MOF/PVA/IL), characterized for its structure and morphology, was assessed for its performance in sensing against various test gases. A detection limit of 1 ppm at 23 °C (room temperature) for H₂S was achieved, with a response time of 12 s. Moreover, (Cu-MOF/PVA/IL) sensor exhibited excellent repeatability, long-term stability, and selectivity towards H₂S gas. The other characteristics of the (Cu-MOF/PVA/IL) sensor include high flexibility, low cost, low-power consumption, and easy fabrication technique, which nominate this sensor as a potential candidate for use in practical industrial applications.

A room temperature (RT) H₂S gas sensor based on organic–inorganic nanocomposites has been developed by incorporating zinc oxide (ZnO) nanoparticles (NPs) into a conductivity-controlled organic polymer matrix. A homogeneous solution containing poly (vinyl alcohol) (PVA) and ionic liquid (IL) and further doped with ZnO NPs was used for the fabrication of a flexible membrane (approx. 200 μm in thickness). The sensor was assessed for its performance against hazardous gases at RT (23 °C). The obtained sensor exhibited good sensitivity, with a detection limit of 15 ppm, and a fast time response (24 ± 3 s) toward H₂S gas. The sensor also showed excellent repeatability, long-term stability and selectivity toward H₂S gas among other test gases. Furthermore, the sensor depicted a high flexibility, low cost, easy fabrication and low power consumption, thus holding great promise for flexible electronic gas sensors.