Urban wet-weather discharges from combined sewer overflows (CSO) and stormwater outlets (SWO) are a potential pathway for micropollutants (trace contaminants) to surface waters, posing a threat to the environment and possible water reuse applications. Despite large efforts to monitor micropollutants in the last decade, the gained information is still limited and scattered. In a metastudy we performed a data-driven analysis of measurements collected at 77 sites (683 events, 297 detected micropollutants) over the last decade to investigate which micropollutants are most relevant in terms of 1) occurrence and 2) potential risk for the aquatic environment, 3) estimate the minimum number of data to be collected in monitoring studies to reliably obtain concentration estimates, and 4) provide recommendations for future monitoring campaigns. We highlight micropollutants to be prioritized due to their high occurrence and critical concentration levels compared to environmental quality standards. These top-listed micropollutants include contaminants from all chemical classes (pesticides, heavy metals, polycyclic aromatic hydrocarbons, personal care products, pharmaceuticals, and industrial and household chemicals). Analysis of over 30,000 event mean concentrations shows a large fraction of measurements (> 50%) were below the limit of quantification, stressing the need for reliable, standard monitoring procedures. High variability was observed among events and sites, with differences between micropollutant classes. The number of events required for a reliable estimate of site mean concentrations (error bandwidth of 1 around the "true" value) depends on the individual micropollutant. The median minimum number of events is 7 for CSO (2 to 31, 80%-interquantile) and 6 for SWO (1 to 25 events, 80%-interquantile). Our analysis indicates the minimum number of sites needed to assess global pollution levels and our data collection and analysis can be used to estimate the required number of sites for an urban catchment. Our data-driven analysis demonstrates how future wet-weather monitoring programs will be more effective if the consequences of high variability inherent in urban wet-weather discharges are considered.

Combined sewer overflows (CSOs) may represent a significant source of pollution, but they are difficult to quantify at a large scale (e.g. regional or national), due to a lack of accessible data. In the present study, we use a large scale, 6-parameter, lumped hydrological model to perform a screening level assessment of different CSO management scenarios for the European Union and United Kingdom, considering prevention and treatment strategies. For each scenario we quantify the potential reduction of CSO volumes and duration, and estimate costs and benefits. A comparison of scenarios shows that treating CSOs before discharge in the receiving water body (e.g. by constructed wetlands) is more cost-effective than preventing CSOs. Among prevention strategies, urban greening has a benefit/cost ratio one order of magnitude higher than grey solutions, due to the several additional benefits it entails. We also estimate that real time control may bring on average a CSO volume reduction of just above 20%. In general, the design of appropriate CSO management strategies requires consideration of context-specific conditions, and is best made in the context of an integrated urban water management plan taking into account factors such as other ongoing initiatives in urban greening, the possibility to disconnect impervious surfaces from combined drainage systems, and the availability of space for grey or nature-based solutions.

An accurate budget of substance emissions is fundamental for protecting freshwater resources. In this context, the European Union asks all member states to report an emission inventory of substances for river basins. The river basin management system MoRE (Modeling of Regionalized Emissions) was developed as a flexible open-source instrument which is able to model pathway-specific emissions and river loads on a catchment scale. As the reporting tool for the Federal Republic of Germany, MoRE is used to model annual emissions of nutrients, heavy metals, micropollutants like polycyclic aromatic hydrocarbons (PAH), Bis(2-ethylhexyl)phthalate (DEHP), and certain pharmaceuticals. Observed loads at gauging stations are used to validate the calculated emissions. In addition to its balancing capabilities, MoRE can consider different variants of input data and quantification approaches, in order to improve the robustness of different modeling approaches and to evaluate the quality of different input data. No programming skills are required to set up and run the model. Due to its flexible modeling base, the effect of reduction measures can be assessed. Within strategic planning processes, this is relevant for the allocation of investments or the implementation of specific measures to reduce the overall pollutant emissions into surface water bodies and therefore to meet the requirements of water policy.

Three lamella settlers were monitored over a period of 4 years. The main objective was to determine removal efficiencies for total suspended solids and associated pollutants. For this purpose a new sampling method based on large volume solid samplers was developed allowing a detailed analysis of solids. With regard to total suspended solids the average removal efficiency of the plants range from 49 to 68%. Similar values could be achieved for phosphorus and heavy metals mainly because of the high portion of fine particles in treatment plants' influent. A clear dependency between solid removal efficiency and the parameters maximum surface load and influent concentration could be observed on a single event basis. The aggregation of all findings result in a recommended maximum design surface loading rate (SLR) of 4 m/h. A solid removal rate of 50%, which is defined as minimum long-term efficiency, can be achieved safely at this SLR. In addition to the definition of the maximum SLR, a proper dissipation of the inflow energy and an equal collection of the clear water above the lamellas turn out to be essential.