This review focuses on a reasoned search for articles to treat contaminated water using hydroxyapatite (HAp)-based compounds. In addition, the fundamentals of heterogeneous photocatalysis were considered, combined with parameters that affect the pollutants’ degradation using hydroxyapatite-based photocatalyst design and strategies of this photocatalyst, and the challenges of and perspectives on the development of these materials. Many critical applications have been analyzed to degrade dyes, drugs, and pesticides using HAp-based photocatalysts. This systematic review highlights the recent state-of-the-art advances that enable new paths and good-quality preparations of HAp-derived photocatalysts for photocatalysis.

The development of photocatalystsor their modification to obtain new photocatalytic performances for the removal of contaminants is a challenge. Hydroxyapatite (HAp), (Ca₁₀(PO₄)₆(OH)₂), is an inorganic component with a high superficial area and low toxicity and the presence of metal in its structure can be an interesting strategy for the photocatalytic approach. This work aimed to synthesize gallium-containing HAp (Ga-HAp) as a promising material for photocatalytic performance. The synthesis was performed by the suspension–precipitation method. The material was characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Morphological analysis employed field emission scanning electron microscope (FESEM) and the elemental analysis by energy-dispersive spectroscopy (EDS). To evaluate the photocatalytic activity, methylene blue (MB) dye was used as a pollutant model under UV light for 120 min. The influence of Ga-HAp concentration (0.25, 0.50, and 1.00 g·L⁻¹) and kinetic reaction was also studied. The Ga-HAp was successfully obtained by the suspension–precipitation method. The structural characterization by XRD and FESEM-EDS elucidated the presence of gallium in the structure of hydroxyapatite. The XPS results indicated the substitution of gallium in the crystal lattice of the material. The discoloration rate of MB dye using Ga-Hap was calculated by pseudo first-order kinetics, and the best rate constant was 7.5 × 10⁻³ min⁻¹ using 1.00 g·L⁻¹ of photocatalyst. The concentration of Ga-HAp influenced the photocatalytic process, because the discoloration rate increased as a function of the concentration of material. Therefore, Ga-HAp is a promising material for environmental remediation.