Bacterial cellulose is an organic product of certain bacterias’ metabolism. It differs from plant cellulose by exhibiting a high strength and purity, making it especially interesting for flexible electronics, membranes for water purification, tissue engineering for humans or even as artificial skin and ligaments for robotic devices. However, bacterial cellulose’s naturally slow growth rate has limited its large-scale applicability to date. Titanium (IV) bis-(ammonium lactato) dihydroxide is shown to be a powerful tool to boost the growth rate of bacterial cellulose production by more than one order of magnitude and that it simultaneously serves as a precursor for the Ti⁴⁺-coordinated cross-linking of the fibers during membrane formation. The latter results in an almost two-fold increase in Young’s modulus (~18.59 GPa), a more than three-fold increase in tensile strength (~436.70 MPa) and even a four-fold increase in toughness (~6.81 MJ m⁻³), as compared to the pure bacterial cellulose membranes.

Nature has evolved hierarchical structures of hybrid materials with excellent mechanical properties. Inspired by nacre’s architecture, a ternary nanostructured composite has been developed, wherein stacked lamellas of 1D vanadium pentoxide nanofibres, intercalated with water molecules, are complemented by 2D graphene oxide (GO) nanosheets. The components self-assemble at low temperature into hierarchically arranged, highly flexible ceramic-based papers. The papers’ mechanical properties are found to be strongly influenced by the amount of the integrated GO phase. Nanoindentation tests reveal an out-of-plane decrease in Young’s modulus with increasing GO content. Furthermore, nanotensile tests reveal that the ceramic-based papers with 0.5 wt% GO show superior in-plane mechanical performance, compared to papers with higher GO contents as well as to pristine V₂O₅and GO papers. Remarkably, the performance is preserved even after stretching the composite material for 100 nanotensile test cycles. The good mechanical stability and unique combination of stiffness and flexibility enable this material to memorize its micro- and macroscopic shape after repeated mechanical deformations. These findings provide useful guidelines for the development of bioinspired, multifunctional systems whose hierarchical structure imparts tailored mechanical properties and cycling stability, which is essential for applications such as actuators or flexible electrodes for advanced energy storage.

Bladder tumor recurrence is a serious problem in uro-oncology, as it increases the risk of fatal progression and makes further surgeries necessary. The possibility of intraoperative tissue differentiation can help for diagnostic purposes as well as for ensuring that the entirety of the tumor is removed. The latter not only differ visually from healthy tissue, but also in their mechanical and electrical properties due to an altered physiology. A possible base for intraoperative tissue differentiation are impedance measurements, which are, however, difficult to obtain passing through the limited space of the urethra. This work presents a comparative study of two impedance sensors, which are obtained by laser direct structuring and rely on a four terminal measurement. The miniaturized sensors are suitable for minimally invasive usage. Circular electrodes are placed in a square for a first sensor, whereas a novel combination of one circular electrode and three concentric rings is designed for the second sensor. For each sensor, the specific geometry factor is determined and the impact of sensitivity towards small conductivity changes inside the tissue investigated. Furthermore, multiple ex vivo measurements on fresh pig bladders are carried out with each sensor. It is shown that both sensors reliably determine tissue impedance data that fit empirical tissue models. Conductivity values close to listed data of human urinary bladder are obtained. Ultimately, the novel ring sensor configuration turns out more favorable in terms of sensitivity distribution and yields more reproducible results than the square electrode arrangement.

High quality and long product life are two fundamental requirements for all circuit carriers, including molded interconnect devices (MID), to find application in various fields, such as automotive, sensor technology, medical technology, and communication technology. When developing a MID for a certain application, not only the design, but also the choice of material as well as the process parameters need to be carefully considered. A well-established method to evaluate the lifetime of such MID, respective of their conductor tracks, is the thermal shock test, which induces thermomechanical stresses upon cycling. Even though this method has numerous advantages, one major disadvantage is its long testing time, which impedes rapid developments. Addressing this disadvantage, this study focuses on the laser direct structuring of thermoplastic LCP Vectra E840i LDS substrates and the subsequent electroless metallization of the commonly used layer system Cu/Ni/Au to force differences in the conductor tracks’ structure and composition. Performing standardized thermal shock tests alongside with flexural fatigue tests, using a customized setup, allows comparison of both methods. Moreover, corresponding thermomechanical simulations provide a direct correlation. The flexural fatigue tests induce equivalent or even higher mechanical stresses at a much higher cycling rate, thus drastically shorten the testing time.

In order to economize injection molded prototypes, additive manufacturing of, e.g., curable plastics based tools, can be employed, which is known as soft tooling. However, one disadvantage of such tools is that the variothermal process, which is needed to produce polymeric parts with small features, can lead to a shorter lifespan of the tooling due to its thermally impaired material properties. Here, a novel concept is proposed, which allows to locally heat the mold cavity via induction to circumvent the thermal impairment of the tooling material. The developed fabrication process consists of additive manufacturing of the tooling, PVD coating the mold cavity with an adhesion promoting layer and a seed layer, electroplating of a ferromagnetic metal layer, and finally patterning the metal layer via laser ablation to enhance the quality and efficiency of the energy transfer as well as the longevity by geometric measures. This process chain is investigated on 2D test specimens to find suitable fabrication parameters, backed by adhesion tests as well as environmental and induction tests. The results of these investigations serve as proof of concept and form the base for the investigation of such induction layers in actual soft tooling cavities.

Due to the superior thermal, mechanical and chemical properties of ceramics, metallized ceramics are widely used as circuit carriers and interconnect devices wherever standard polymer-based circuit boards come to their limits. 2D metallization represents the current state-of-the-art. The metallization of 3D shaped ceramics cannot be achieved with standard metallization techniques and is still a field of research. In this study laser induced direct metallization (LDM) is applied, where a pulsed laser is used to locally activate the surface of a Cr₂O₃ doped ZTA ceramic. Subsequently a selective electroless copper plating on the laser irradiated areas is performed. Laser power, pulse repetition frequency, pulse overlap and the amount of surpasses were varied systematically in order to determine the parametric sensitivity of the ablation and metallization behavior for pulsed infrared laser structuring. It was found that ablation is necessary for the metallization and the peak fluence is the governing factor for the ablation and metallization process. It was further shown, that the ablation can be well predicted with an accumulated fluence which includes the pulse overlap. 3D ceramic substrates were successfully metallized applying an optimized set of laser parameters.