Flexible pressure sensors that can maintain their pressure sensing ability with arbitrary deformation play an essential role in a wide range of applications, such as aerospace, prosthetics, robotics, healthcare, human–machine interfaces, and electronic skin. Flexible pressure sensors with diverse conversion principles and structural designs have been extensively studied. At present, with the development of 5G and the Internet of Things, there is a huge demand for flexible pressure sensor arrays with high resolution and sensitivity. Herein, we present a brief description of the present flexible pressure sensor arrays with different transduction mechanisms from design to fabrication. Next, we discuss the latest progress of flexible pressure sensor arrays for applications in human–machine interfaces, healthcare, and aerospace. These arrays can monitor the spatial pressure and map the trajectory with high resolution and rapid response beyond human perception. Finally, the outlook of the future and the existing problems of pressure sensor arrays are presented.
Tribological properties of tread rubber is a key problem for the safety and durability of large aircraft tires. So, new molecular models of carbon nanotube (CNT) reinforced vulcanized natural rubber (VNR) composites have been developed to study the enhanced tribological properties and reveal the reinforced mechanism. Firstly, the dynamic process of the CNT agglomeration is discussed from the perspectives of fractional free volume (FFV) and binding energy. Then, a combined explanation of mechanical and interfacial properties is given to reveal the CNT-reinforced mechanism of the coefficient of friction (COF). Results indicate that the bulk, shear and Young’s modulus increase with the increasement of CNT, which are increasement of 19.13%, 21.11% and 26.89% in 15 wt.% CNT/VNR composite compared to VNR; the predicted results are consistent with the existing experimental conclusions, which can be used to reveal the CNT-reinforced mechanism of the rubber materials at atomic scale. It can also guide the design of rubber material prescription for aircraft tire. The molecular dynamics study provides a theoretical basis for the design and preparation of high wear resistance of tread rubber materials.
Inspired by traditional solvents for carboxylic acid extraction being not environmentally friendly, novel hydrophobic deep eutectic solvents (DESs) based on amides as hydrogen bond acceptors (HBAs) and terpenes as hydrogen bond donors (HBDs) were proposed as sustainable solvents. The structures were characterized by 1H NMR and GC-MS, meanwhile the formation mechanism was revealed by electrostatic potential (ESP) analysis. In addition, the partition coefficients and separation factors of lactic, malic, and tartaric acids (LA, MA, and TA) in novel DESs were tested by a simple solvent extraction approach. What's more, the contributions of HBAs and HBDs in improving the selective separation of carboxylic acids were confirmed by multiscale exploration and experimental research. HBAs increase the partition coefficient via forming double hydrogen bonds with LA, MA, and TA. HBDs improve the selectivity by competition with these acids. This finding can serve as a blueprint for the design of greener solvents for the selective separation of carboxylic acids in bioprocesses.
Flexible pressure sensors have garnered much attention recently owing to their prospective applications in fields such as structural health monitoring. Capacitive pressure sensors have been extensively researched due to their exceptional features, such as a simple structure, strong repeatability, minimal loss and temperature independence. Inspired by the skin epidermis, we report a high-sensitivity flexible capacitive pressure sensor with a broad detection range comprising a bioinspired spinosum dielectric layer. Using an abrasive paper template, the bioinspired spinosum was fabricated using carbon nanotube/polydimethylsiloxane (CNT/PDMS) composites. It was observed that nanocomposites comprising 1 wt% CNTs had excellent sensing properties. These capacitive pressure sensors allowed them to function at a wider pressure range (~500 kPa) while maintaining sensitivity (0.25 kPa−1) in the range of 0–50 kPa, a quick response time of approximately 20 ms and a high stability even after 10,000 loading–unloading cycles. Finally, a capacitive pressure sensor array was created to detect the deformation of tires, which provides a fresh approach to achieving intelligent tires.
Nitrile Butadiene Rubber (NBR) is widely used as a sealing material due to its excellent mechanical properties and good oil resistance. However, when using NBR material, the seal structure is unable to avoid the negative effects of rubber aging. Hence, the influence of oil and thermal aging on the characteristics of NBR seals was studied by coupling the mechanical behavioral changes with the tribological behavioral changes of NBR in oil and the thermal environment. For this paper, aging testing and compression testing of NBR were carried out. Additionally, friction testing between friction pairs under different aging times was carried out. The surface morphology of the NBR working surface under different aging conditions was also observed. Finally, coefficients of different test conditions were introduced into the finite element model of NBR seals. It can be seen from the results that the elastic modulus increased with the increase in aging time in the thermal oxidative aging testing. The elastic modulus after 7 days of thermal oxidative aging increased by 135.45% compared to the unaged case, and the elastic modulus after 7 days of oil aging increased by 15.03% compared to the unaged case. The compression set rate of NBR increased significantly with the increase in aging time and temperature. The coefficient of friction (COF) between friction pairs increased first and then decreased with the increase in aging time. The maximum contact pressure decreased by 2.43% between the shaft and sealing ring and decreased by 4.01% between the O-ring and groove. The proportion of the effective sealing area decreased by 3.05% between the shaft and sealing ring and decreased by 6.11% between the O-ring and groove. Furthermore, the sealing characteristics between the O-ring and groove were better than those between the shaft and sealing ring.
Elastomeric polymers have gained significant attention in the field of flexible electronics. The investigation of the electro-mechanical response relationship between polymer structure and flexible electronics is in increasing demand. This study investigated the factors that affect the performance of flexible capacitive pressure sensors using the finite element method (FEM). The sensor employed a porous elastomeric polymer as the dielectric layer. The results indicate that the sensor’s performance was influenced by both the structural and material characteristics of the porous elastomeric polymer. In terms of structural characteristics, porosity was the primary factor influencing the performance of sensors. At a porosity of 76%, the sensitivity was 42 times higher than at a porosity of 1%. In terms of material properties, Young’s modulus played a crucial role in influencing the performance of the sensors. In particular, the influence on the sensor became more pronounced when Young’s modulus was less than 1 MPa. Furthermore, porous polydimethylsiloxane (PDMS) with porosities of 34%, 47%, 67%, and 72% was fabricated as the dielectric layer for the sensor using the thermal expansion microsphere method, followed by sensing capability testing. The results indicate that the sensor’s sensitivity was noticeably influenced within the high porosity range, aligning with the trend observed in the simulation.