Among the different thermo-chemical recycling routes for plastic waste valorization, gasification is one of the most promising, converting plastic waste into syngas (H₂+CO) and energy in the presence of an oxygen-rich gas. Plastic waste gasification is associated with many different complexities due to the multi-scale nature of the process, the feedstock complexity (mixed polyolefins with different contaminations), intricate reaction mechanisms, plastic properties (melting behavior and molecular weight distribution), and complex transport phenomena in a multi-phase flow system. Hence, creating a reliable model calls for an extensive understanding of the phenomena at all scales, and more advanced modeling approaches than those applied today are required. Indeed, modeling of plastic waste gasification (PWG) is still in its infancy today. Our review paper shows that the thermophysical properties are rarely properly defined. Challenges in this regard together with possible methodologies to decently define these properties have been elaborated. The complexities regarding the kinetic modeling of gasification are numerous, compared to, e.g., plastic waste pyrolysis, or coal and biomass gasification, which are elaborated in this work along with the possible solutions to overcome them. Moreover, transport limitations and phase transformations, which affect the apparent kinetics of the process, are not usually considered, while it is demonstrated in this review that they are crucial in the robust prediction of the outcome. Hence, possible approaches in implementing available models to consider these limitations are suggested. Finally, the reactor-scale phenomena of PWG, which are more intricate than the similar processes—due to the presence of molten plastic—are usually simplified to the gas-solid systems, which can result in unreliable modeling frameworks. In this regard, an opportunity lies in the increased computational power that helps improve the model’s precision and allows us to include those complexities within the multi-scale PWG modeling. Using the more accurate modeling methodologies in combination with multi-scale modeling approaches will, in a decade, allow us to perform a rigorous optimization of the PWG process, improve existing and develop new gasifiers, and avoid fouling issues caused by tar.

The performance of a conventional fluidized bed and a rotating fluidized bed in a static geometry (RFB-SG) for the drying of woody biomass is experimentally studied. The performance with respect to the specific biomass drying rate, product uniformity, and air utilization is evaluated. RFB-SGs are shown to intensify the drying process by easily one order of magnitude, due to a combination of increased gas–solid slip velocities and improved particle bed density and uniformity. The cost in terms of increased and less efficient air utilization can be minimized by optimizing the RFB-SG drying chamber design.

The intensification of interfacial mass, heat, and momentum transfer makes vortex chambers potentially interesting for the efficient drying of paddy, allowing shorter drying times and/or more compact equipment. The presence of a shell introduces particular challenges. Intraparticle diffusion limitations are strong and may reduce the advantage from intensified interfacial mass and heat transfer and the efficiency of air usage. Furthermore, high shear and normal stresses in the fast rotating particle bed may cause damage to the paddy shell, posing problems for transport and storage. With these specific aspects in mind, the use of vortex chambers for paddy drying is experimentally evaluated.

In this paper, an intensified spray-drying process in a novel Radial Multizone Dryer (RMD) is analyzed by means of CFD. A three-dimensional Eulerian–Lagrangian multiphase model is applied to investigate the effect of solids outlet location, relative hot/cold airflow ratio, and droplet size on heat and mass transfer characteristics, G-acceleration, residence time, and separation efficiency of the product. The results indicate that the temperature pattern in the dryer is dependent on the solids outlet location. A stable, symmetric spray behavior with maximum evaporation in the hot zone is observed when the solids outlet is placed at the periphery of the vortex chamber. The maximum product separation efficiency (85 wt %) is obtained by applying high G-acceleration (at relative hot/cold ratio of 0.75) and narrow droplet size distribution (45–70 µm). The separation of different sized particles with distinct drying times is also observed. Smaller particles (<32 µm) leave the reactor via the gas outlet, while the majority of big particles leave it via the solids outlet, thus depicting in situ particle separation. The results revealed the feasibility and benefits of a multizone drying operation and that the RMD can be an attractive solution for spray drying technology.