This study presents the results of an experimental campaign on the use of municipal solid waste incinerator bottom ash (MIBA) and fly ash (FA) as precursors for the production of alkali-activated materials. MIBA was subjected to a pre-treatment stage in response to two issues: high metallic aluminum content, which reacts in a high pH solution, releasing hydrogen; and low amorphous content of silica-, aluminum- and calcium-bearing phases, which translates into a limited formation of reaction products. The proposed pre-treatment stage oxidizes most of the metallic aluminum fraction and compensates for the low reactivity of the material via the formation of additional reactants. Different combinations of MIBA and FA were tried—mass-based ratios of 0/100, 25/75, 50/50, 75/25, and 100/0 for MIBA/FA. Two mix designs of the alkaline activator with sodium hydroxide and sodium silicate were evaluated by varying the Na₂O/binder and SiO₂/Na₂O ratios. These mortars were tested in the fresh and hardened state. The results showed that the pre-treatment stage was effective at stabilizing the dimensional variation of MIBA. Despite the lower reactivity of MIBA, mortars with 50/50 of MIBA/FA presented a maximum 28-day compressive strength of 25.2 MPa, higher than the 5.7 MPa of mortars made with MIBA only.

This study aims to evaluate the potential of incorporating fly ash (FA) and municipal solid waste incinerator bottom ash (MIBA) as a partial substitute of cement in the production of self-compacting concrete mixes through an experimental campaign in which four replacement levels (i.e., 10% FA + 20% MIBA, 20% FA + 10% MIBA, 20% FA + 40% MIBA and 40% FA + 20% MIBA, apart from the reference concrete) were considered. Compressive and tensile strengths, Young’s modulus, ultra-sonic pulse velocity, shrinkage, water absorption by immersion, chloride diffusion coefficient and electrical resistivity were evaluated for all concrete mixes. The results showed a considerable decline in both mechanical and durability-related performances of self-compacting concrete with 60% of substitution by MIBA mainly due to the aluminium corrosion chemical reaction. However, workability properties were not significantly affected, exhibiting values similar to those of the control mix.

Pre-treated incinerator bottom ash was used as a precursor of alkali-activated mortars. Control mortars were produced using coal fly ash. Different combinations of alkaline activator were tested (sodium oxide/binder ratio (4%, 6%, 8%, 10% and 15%) and silicon dioxide/sodium oxide ratio (0, 0.5, 1.0, 1.5 and 2.0)) and the influence of these on the mortar's mechanical performance was evaluated. The mortars were tested in both fresh (for density and workability) and hardened states (for dry density, compressive and flexural strengths and modulus of elasticity) after 7, 28, 91 and 182 days. The first stage of work was precursor pre-treatment in a sodium hydroxide solution to prevent the expansion of fresh specimens due to the reaction of aluminium with the alkaline activator. The pre-treatment was effective in preventing excessive hydrogen gas generation during setting, leading to dimensional stability and improved strength. Different optimum sodium oxide contents were observed after 28 days (i.e. 15% for fly ash specimens and 8% for bottom ash specimens). The results of a simplified life-cycle assessment showed that such mixes exhibited lower overall carbon dioxide emissions when compared with cement-based counterparts. However, this trend was reversed with increasing contents of sodium hydroxide and sodium silicate.

The incorporation of calcined sludge (CS) from water treatment plants and nitrophosphogypsum (NPG) into mortar mixtures has been investigated as a potential strategy to reduce the consumption of ordinary Portland cement (OPC) and subsequently lower the carbon footprint of construction materials. Two scenarios were subjected to analysis: in the first, CO₂ emissions resulting from the treatment of NPG and CS were considered; in the second, emissions were considered negligible due to the reduced energy demand of waste treatment processes compared to OPC production. The chemical composition and mechanical properties of the mortars were evaluated through the use of X-ray fluorescence (XRF) and compressive strength testing. The mortar mixtures were prepared with a water-to-binder ratio of 0.485 in accordance with the ASTM standards. The mortar mixture containing 5% NPG and 5% CS exhibited a 6.65% increase in compressive strength, reaching 38.96 MPa after 90 days. Despite a slight reduction in early strength, long-term performance was enhanced by the formation of additional calcium silicate hydrates. Regarding sustainability, a reduction of 62.06 kg CO₂ per cubic meter of mortar was achieved in both scenarios, with more substantial reductions in Scenario 2. These results show that incorporating NPG and CS supports the circular economy by utilizing industrial by-products and provides a sustainable alternative to OPC, significantly reducing CO₂ emissions while maintaining or enhancing mechanical performance, thereby aligning with global efforts towards eco-friendly construction practices.