The main objective of this study is treatment and characterization of phosphorus from synthetic wastewater using aluminum electrodes in the electrocoagulation process. EC experimental setups were designed and different parameters were optimized. The maximum amounts of phosphorus removal efficiencies were observed at pH 7. The phosphorus removal efficiency increases from 85.16 to 97.65% as the temperature increases from 15 to 45 °C, beyond this temperature, there is small effect on removal efficiency. Pollutant removal efficiency increases with an increase in the electrolysis time. At lower initial concentrations the removal efficiencies reached to their maximum values while at the highest initial concentration, the phosphorus removal efficiency was decreased. The increase of current density improves the efficiency of phosphorus removal. Energy and aluminum consumption decreases with increasing initial concentration of phosphorus. Field Emission Scanning Electron Microscope (FESEM) image analysis demonstrated very fine structures for aluminum hydroxide/oxyhydroxides and aluminum phosphate. The existence of the different elemental composition in the sludge was proved by the help of Energy Dispersive X-ray Analysis (EDXS), indicating that the aluminum, oxygen and phosphorus were present in the product. From X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR) and Raman analyses of the sludge product, it is concluded that the chemical speciation of the by-products can be mostly aluminum hydroxide and aluminum phosphate.

Excess agrochemicals input from agricultural activities and industrial effluent around Lake Ziway catchment can pose a serious threat on the lake ecosystem. Lake Ziway is a shallow freshwater lake found in the northern part of the Ethiopian Rift Valley. It is characterized as semi-arid to sub-humid type of climate. Expansions of the flower industry, widespread fisheries, intensive agricultural activities, fast population growth lead to deterioration of water quality and depletion of aquatic biota. The spatial and temporal variations of selected water quality parameters were evaluated using multivariate techniques. The data were collected from nine sampling stations during dry and wet seasonal basis for analysis of fifteen water quality parameters. The physicochemical parameters were measured in-situ with portable multimeter and nutrients were determined by following the standard procedures outlined in the American Public Health Association using UV/Visible spectrophotometer. Mean nutrient concentrations showed increasing trend in all seasons. These sites were also characterized by high electrical conductivity and total dissolved solid (TDS). All the nine sampling sites were categorized into three pollution levels according to their water quality features using cluster analysis (CA). Accordingly, sampling sites Fb and Ketar River (Kb) are highly and moderately polluted in both seasons, respectively. On the other hand, sampling sites at the center (C), Meki river mouth (Ma), Ketar river mouth (Ka), Meki River (Mb), Korekonch (K_o) and Fa in dry season and Ka, C, Ma, Ko, Bulbula river mouth (B) and Fa during wet season were less polluted. Principal component analysis (PCA) analysis also showed the pollutant sources were mainly from Fb during dry season Mb and Kb during wet season. The values of comprehensive pollution index illustrated the lake is moderately and slightly polluted in dry and wet seasons, respectively. Comparatively, the pollution status of the lake is high around floriculture effluent discharge site and at the two feeding rivers (Kb and Mb) due to increasing trends in agrochemical loads. In order to stop further deterioration of the lake water quality and to eventually restore the beneficial uses of the lake, management of agrochemicals in the lake catchments should be given urgent priority.

Organic matter and some selected metals (As, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, Pb, and Zn) were measured from water and sediment while plant samples from the inlet to the outlet sampling sites using standard procedures from three compartments (water, sediment, and macrophytes) of Yitamot wetland. Findings indicated that the mean concentration of COD in water was in the range of 5.25 mg/L and 208.25 mg/L and showed a significant and exponential decrease along the subsequent sampling sites (P < 0.05). The mean concentrations of K, As, Cd, and Cr (82.192 mg/kg, 0.730 mg/kg, 0.06 mg/kg, and 19.776 mg/kg, respectively) were significantly lower values in the outlet than in the inlet of the sediment samples (P < 0.05). All the metal concentrations in the aboveground tissue of macrophytes were significantly lower at the outlet sample site (P < 0.05) indicating that these compartments are contributing to the retention of metals and organic matter present in wastewater discharged in the wetland through sinks and conversions of these compounds. However, there was no significant removal effect for heavy metals like Fe, Zn, and As (P > 0.05). This is a pointer to the fact that natural wetlands can be used effectively for wastewater treatment with strong monitoring programs and ecological indicators for the sustainable management and conservation of the flora and fauna present in it.

Background: The majority of existing industries in Ethiopia discharge untreated effluents into nearby water bodies, streams and open land. The wastewater generated by Gondar malt factory (GMF) was disposed freely and join a natural wetland implemented for the treatment of the wastewater. The objective of the study was to analyze and characterize wastewater from GMF and to evaluate the effectiveness of the wetland for the treatment purpose. Methods: Different Physicochemical quality indicators (color, turbidity pH, temperature, Total Dissolved solids, Total Suspended solids, total solid, conductivity, alkalinity, hardness, nitrate, phosphate, sulfate, free chlorides, heavy metals-(Cd, Cr, Fe, Mn, and Pb)and Biological Oxygen Demand were measured according to the standard procedures. Data was analyzed using Statistical Package for Social Sciences (SPSS-25). Analysis of Variance (ANOVA) was used to find whether significant differences existed in the different sampling stations for the parameters studied. P value less than 0.05 was considered to show significant difference. Results: The results of this study revealed that most of the quality indicators were improved in value after the water passed through the wetland except for alkalinity M, sulfite, Mn, temperature and pH. From ANOVA result, it was noted that there was a significant mean difference between the stations except for chromium, manganese and lead. The result showed that the wetland plays a great role in the removal of pollutants where the best performance was obtained at removal efficiency of 96.188% PO₄^HR_,75.63% Nitrate,>99% Cl_2, ammonia and nitrite 99.99%, 92.77% sulfate,84.36% Total hardness,87.43% color, and for others it is ranged between 30 and 60%. Conclusion: the study concluded that GMF wetland was almost effective and had potential in treatment of the wastewater from the discharging facilities (especially for nutrients, alkalinity P, hardness, color and chloride). It is recommended that wetlands should be conserved and used as wastewater treatment facility.