We observe the excitation of collective modes in the terahertz (THz) range driven by the recently discovered Néel spin-orbit torques (NSOTs) in the metallic antiferromagnet . Temperature-dependent THz spectroscopy reveals a strong absorption mode centered near 1 THz, which upon heating from 4 to 450 K softens and loses intensity. A comparison with the estimated eigenmode frequencies implies that the observed mode is an in-plane antiferromagnetic resonance (AFMR). The AFMR absorption strength exceeds those found in antiferromagnetic insulators, driven by the magnetic field of the THz radiation, by 3 orders of magnitude. Based on this and the agreement with our theory modeling, we infer that the driving mechanism for the observed mode is the current-induced NSOT. Here the electric field component of the THz pulse drives an ac current in the metal, which subsequently drives the AFMR. This electric manipulation of the Néel order parameter at high frequencies makes a prime candidate for antiferromagnetic ultrafast memory applications.
We present the investigation of a monoclinic compound SeCuO using x-ray powder diffraction, magnetization, torque, and electron-spin-resonance. Structurally based analysis suggests that SeCuO can be considered as a three-dimensional network of tetramers. The values of intratetramer exchange interactions are extracted from the temperature dependence of the susceptibility and amount to K. The intertetramer coupling leads to the development of long-range antiferromagnetic order at K. An unusual temperature dependence of the effective tensors is observed, accompanied with a rotation of macroscopic magnetic axes. We explain this unique observation as due to site-selective quantum correlations.
Hierarchical porous carbons are known to enhance the electrochemical features of electrodes in electrochemical capacitors. However, the contribution of surface oxygen and the resulting functionalities and wettability, along with the role of electrical conductivity and degree of amorphous or crystalline nature in the micro-mesoporous carbons, are not yet clear. This article considers the effect of carbonisation temperature (500–900 °C) and the type of activation (CO2, KOH) on the properties mentioned above in case of carbon xerogels (CXs) to understand the resulting electrochemical performances. Depending on the carbonisation temperature, CX materials differ in micropore surface area (722–1078 m2 g−1) while retaining a mesopore surface area ~300 m2 g−1, oxygen content (3–15%, surface oxygen 0–7%), surface functionalities, electrical conductivity (7 × 10−6–8 S m−1), and degree of amorphous or crystalline nature. Based on the results, electrochemical performances depend primarily on electrical conductivity, followed by surface oxygen content and meso-micropore connectivity. The way of activation using a varied extent of CO2 exposure and KOH concentrations played differently in CX in terms of pore connectivity from meso- to micropores and their contributions and degree of oxidation, and resulted in different electrochemical behaviours. Such performances of activated CXs depend solely on micro-mesopore features.
We have studied the frequency and voltage dependences of voltage-induced torsional strains in orthorhombic [V. Y. Pokrovskii, S. G. Zybtsev, and I. G. Gorlova, Phys. Rev. Lett. 98, 206404 (2007)] by measuring the modulation of the resonant frequency of an rf cavity containing the sample. The strain has an onset voltage below the charge-density-wave (CDW) threshold voltages associated with changes in shear compliance and resistance, suggesting that the strain is associated with polarization of the CDW rather than CDW current. Measurements with square-wave voltages show that the strain is very sluggish, not even reaching its dc value at a frequency of 0.1 Hz, but the dynamics appears to be very sample dependent. By applying oscillating torque while biasing the sample with a dc current, we have also looked for strain-induced voltage in the sample; none is observed at the low biases where the voltage-induced strains first occur, but an induced voltage is observed at higher biases, probably associated with a strain-dependent CDW conductance.
We report on the heat capacity investigation of Cu55Hf45−xTix metallic glasses. The most appropriate procedure to estimate low temperature electronic and phonon contributions has been determined. Both contributions exhibit monotonous Ti concentration dependence, demonstrating that there is no relation of either the electron density of states at the Fermi level or the Debye temperature to the increased glass forming ability in the Ti concentration range x = 15–30. The thermodynamic parameters (e.g., reduced glass temperature) remain better indicators in assessing the best composition for bulk metallic glass formation.