Bi₂MoO₆–RGO composite nanoplates with good uniformity and highly oriented growth of the active lattice were successfully synthesized by a simple hydrothermal process with the assistance of graphene oxide. Reduced graphene oxide was observed to be formed on the surface of the Bi₂MoO₆ nanoplates after the hydrothermal treatment. A remarkable enhancement in the visible-light-driven (VLD) photocatalytic destruction of bacteria was observed over the Bi₂MoO₆–RGO composite when compared to pure Bi₂MoO₆.

Herein, combining photocatalysis and Fenton oxidation, a photo-assisted Fenton system was conducted using Fe-doped Bi₄O₅Br₂ as a highly efficient photocatalyst to realize the complete degradation of Tetracycline antibiotics under visible light. It has been observed that the optimized photocatalyst 5%Fe-doped Bi₄O₅Br₂ exhibits a degradation efficiency of 100% for Tetracycline with H₂O₂ after 3 h visible-light irradiation, while a degradation percentage of 59.8% over the same photocatalyst and 46.6% over pure Bi₄O₅Br₂ were obtained without the addition of H₂O₂ (non-Fenton process). It is unambiguous that a boost photo-assisted Fenton system for the degradation of Tetracycline has been established. Based on structural analysis, it demonstrated that the Fe atoms in place of the Bi sites may result in the distortion of the local structure, which induced the occurrence of the spontaneous polarization and thus enhanced the built-in electric field. The charge separation efficiency is enhanced, and the recombination of electrons and holes is inhabited so that more charges are generated to reach the surface of the photocatalyst and therefore improve the photocatalytic degradation efficiency. Moreover, more Fe (II) sites formed on the 5%Fe-Bi₄O₅Br₂ photocatalyst and facilitated the activation of H₂O₂ to form oxidative species, which greatly enhanced the degradation efficiency of Tetracycline.