The paper evaluates the performance of an adsorption-based technology for CO₂ capture directly from the air at the industrial scale. The approach is based on detailed mass and energy balance dynamic modeling of the vacuum temperature swing adsorption (VTSA) process in Aspen Adsorption software. The first step of the approach aims to validate the modeling thanks to published experimental data for a lab-scale bed module in terms of mass transfer and energy performance on a packed bed using amine-functionalized material. A parametric study on the main operating conditions, i.e., air velocity, air relative moisture, air temperature, and CO₂ capture rate, is undertaken to assess the global performance and energy consumption. A method of up-scaling the lab-scale bed module to industrial module is exposed and mass transfer and energy performances of the industrial module are provided. The scale up from lab scale to the industrial size is conservative in terms of thermal energy consumption while the electrical consumption is very sensitive to the bed design. Further study related to the engineering solutions available to reach high global gas velocity are required. This could be offered by monolith-shape adsorbents.

This article addresses the one-dimensional modeling of a charring polymer decomposition in the cone calorimeter used to reproduce at bench scale the radiative heating from a fire. The rate-controlling phenomena are first discussed in a preliminary analysis of dimensionless numbers. Then, the role of three critical assumptions is highlighted by simulations: (1) transport of the gaseous products within the material or instantaneous release of gaseous products, (2) volume variation or constant volume, and (3) absorption of applied heat flux at the exposed face or through the thickness. Their influence in thermally thick regime is shown in particular on mass loss rate and time to extinction. Under the conditions tested, the influence of internal transport by convection on mass loss rate and time to extinction is minor. The assumption of constant volume appears to have a moderate influence on the mass loss rate and time to extinction. Variations of optical properties affect the numerical results by an increase of the maximum peak of mass loss rate and a decrease of time to extinction. Finally, the effects of applied heat flux and initial material thickness on the mass loss rate and time to extinction are important. With a higher heat flux or a smaller thickness, the decomposition is earlier, faster, and more intense.