Laboratory Magnetic Phenomena in Microelectronics, Kotelnikov Institute of Radioengineering and Electronics of Russian Academy of Sciences, 11/7 Mokhovaya st., 125009 Moscow, Russia
Dr. Alexey Mashirov
Laboratory Magnetic Phenomena in Microelectronics, Kotelnikov Institute of Radioengineering and Electronics of Russian Academy of Sciences, 11/7 Mokhovaya st., 125009 Moscow, Russia
Measurements of the adiabatic temperature change (ΔT) and the specific heat transfer (ΔQ) of Ni2.18Mn0.82Ga Heusler alloy were taken in order to quantify the direct giant magnetocaloric effect of the alloy when it is in the vicinity of magneto-structural phase transition (PT) from paramagnetic austenite to ferromagnetic martensite, and their results are presented. A new vacuum calorimeter was used to simultaneously measure ΔT and ΔQ of magnetocaloric materials with a Bitter coil magnet in fields of up to H = 140 kOe. Other thermomagnetic properties of this alloy were investigated using standard differential scanning calorimetry and PPMS equipment. The maximal values of magnetocaloric effect in H = 140 kOe were found to be ΔT = 8.4 K at initial temperature 340 K and ΔQ = 4900 J/kg at 343 K. Using this direct method, we show that the alloy indeed demonstrates the largest value of ΔQ as compared with previously published results for direct measurements of magnetocaloric materials, even though at 140 kOe the magnetic field-induced magnetostructural PT is still not complete.
High cooling power of magnetocaloric refrigeration can be achieved only at large amounts of heat, which can be transferred in one cycle from cold end hot end at quasi-isothermal conditions. The simple and robust experimental method of direct measuring of the transferred heat of materials with magnetocaloric effect (MCE) in thermal contact with massive copper block with definite heat capacity in quasi-isothermal regime was proposed. The vacuum calorimeter for the specific transferred heat ΔQ and adiabatic temperature change ΔT measurements of MCE materials in the fields of Bitter coil magnet up to H = 140 kOe was designed and tested on samples of Ni43Mn37.9In12.1Co7 Heusler alloy with inverse MCE in the vicinity of meta-magnetostructural phase transition (PT). It was found, that the magnetic field H = 80 kOe produces complete PT from martensite to austenite with ΔQ = - 1600 J/kg at initial temperature 273 K.
1 November 2013 in Journal of Alloys and Compounds