Hydrogel-based wastewater treatment technologies show certain outstanding features, which include exceptional efficiency, sustainability, reusability, and the precise targeting of specific contaminants. Moreover, it becomes possible to minimize the environmental impact when using these materials. Their flexibility, low energy consumption, and adaptability to meet specific requirements for different purposes offer significant advantages over traditional methods like activated carbon filtration, membrane filtration, and chemical treatments. Recent advancements in hydrogel technology, including new production methods and hybrid materials, enhance their ability to efficiently adsorb contaminants without altering their biocompatibility and biodegradability. Therefore, innovative materials that are ideal for sustainable water purification were developed. However, these materials also suffer from several limitations, mostly regarding the scalability, long-term stability in real-world systems, and the need for precise functionalization. Therefore, overcoming these issues remains a challenge. Additionally, improving the efficiency and cost-effectiveness of regeneration methods is essential for their practical use. Finally, assessing the environmental impact of hydrogel production, use, and disposal is crucial to ensure these technologies are beneficial in the long run. This review summarizes recent advancements in developing polymer-based hydrogels for wastewater treatment by adsorption processes to help us understand the progress made during recent years. In particular, the studies presented within this work are compared from the point of view of the synthesis method, raw materials used such as synthetic/natural or hybrid networks, and the targeted class of pollutants—dyes or heavy metal ions. In several sections of this paper, discussions regarding the most important properties of the newly emerged adsorbents, e.g., kinetics, the adsorption capacity, and reusability, are also discussed.

A series of poly(butylene sebacate) (PBSe) aliphatic polyesters were successfully synthesized by the melt polycondensation of sebacic acid (Se) and 1,4-butanediol (BDO), two monomers manufactured on an industrial scale from biomass. The number average molecular weight (M_n) in the range from 6116 to 10,779 g/mol and the glass transition temperature (T_g) of the PBSe polyesters were tuned by adjusting the feed ratio between the two monomers. Polylactic acid (PLA)/PBSe blends with PBSe concentrations between 2.5 to 20 wt% were obtained by melt compounding. For the first time, PBSe’s effect on the flexibility and toughness of PLA was studied. As shown by the torque and melt flow index (MFI) values, the addition of PBSe endowed PLA with both enhanced melt processability and flexibility. The tensile tests and thermogravimetric analysis showed that PLA/PBSe blends containing 20 wt% PBSe obtained using a BDO molar excess of 50% reached an increase in elongation at break from 2.9 to 108%, with a negligible decrease in Young’s modulus from 2186 MPa to 1843 MPa, and a slight decrease in thermal performances. These results demonstrated the plasticizing efficiency of the synthesized bio-derived polyesters in overcoming PLA’s brittleness. Moreover, the tunable properties of the resulting PBSe can be of great industrial interest in the context of circular bioeconomy.

Chitosan is used in medicine, pharmaceuticals, cosmetics, agriculture, water treatment, and food due to its superior biocompatibility and biodegradability. Nevertheless, the complex and relatively expensive extraction costs hamper its exploitation and, implicitly, the recycling of marine waste, the most abundant source of chitosan. In the spirit of developing environmental-friendly and cost-effective procedures, the present study describes one method worth consideration to deliver calcium-carbonate-enriched chitosan from shrimp shell waste, which proposes to maintain the native minerals in the structure of chitin in order to improve the thermal stability and processability of chitosan. Therefore, a synthesis protocol was developed starting from an optimized deacetylation procedure using commercial chitin. The ultimate chitosan product from shrimp shells, containing native calcium carbonate, was further compared to commercial chitosan and chitosan synthesized from commercial chitin. Finally, the collected data during the study pointed out that the prospected method succeeded in delivering calcium-carbonate-enriched chitosan with high deacetylation degree (approximately 75%), low molecular weight (Mn ≈ 10.000 g/ mol), a crystallinity above 59 calculated in the (020) plane, high thermal stability (maximum decomposition temperature over 300 °C), and constant viscosity on a wide range of share rates (quasi-Newtonian behavior), becoming a viable candidate for future chitosan-based materials that can expand the application horizon.

The present work aims to study the influence of ammonium-quaternary monomers and chitosan, obtained from different sources, upon the effect of semi-interpenetrating polymer network (semi-IPN) hydrogels upon the removal of waterborne pathogens and bacteria from wastewater. To this end, the study was focused on using vinyl benzyl trimethylammonium chloride (VBTAC), a water-soluble monomer with known antibacterial properties, and mineral-enriched chitosan extracted from shrimp shells, to prepare the semi-IPNs. By using chitosan, which still contains the native minerals (mainly calcium carbonate), the study intends to justify that the stability and efficiency of the semi-IPN bactericidal devices can be modified and better improved. The new semi-IPNs were characterized for composition, thermal stability and morphology using well-known methods. Swelling degree (SD%) and the bactericidal effect assessed using molecular methods revealed that hydrogels made of chitosan derived from shrimp shell demonstrated the most competitive and promising potential for wastewater (WW) treatment.

This work reports the construction of a bicomponent scaffold co-loaded with both a prodrug and a drug (BiFp@Ht) as an efficient platform for wound dressing, by combining the electrospinning and 3D-printing technologies. The outer component consisted of a chitosan/polyethylene oxide-electrospun membrane loaded with the indomethacin–polyethylene glycol–indomethacin prodrug (Fp) and served as a support for printing the inner component, a gelatin methacryloyl/sodium alginate hydrogel loaded with tetracycline hydrochloride (Ht). The different architectural characteristics of the electrospun and 3D-printed layers were very well highlighted in a morphological analysis performed by Scanning Electron Microscopy (SEM). In vitro release profile studies demonstrated that both Fp and Ht layers were capable to release the loaded therapeutics in a controlled and sustained manner. According to a quantitative in vitro biological assessment, the bicomponent BiFp@Ht scaffold showed a good biocompatibility and no cytotoxic effect on HeLa cell cultures, while the highest proliferation level was noted in the case of HeLa cells seeded onto an Fp nanofibrous membrane. Furthermore, the BiFp@Ht scaffold presented an excellent antimicrobial activity against the E. coli and S. aureus bacterial strains, along with promising anti-inflammatory and proangiogenic activities, proving its potential to be used for wound dressing.

In the present work, solvent casting and Pickering emulsion methods are studied to enhance the mechanical properties of polylactic acid (PLA) composites containing surface-modified cellulose nanomaterials. To enhance the compatibility and the adhesion at the interface, cellulose nanocrystal (CNC) was functionalized by 2,4-methylene diphenyl diisocyanate (MDI) and castor oil. Their results demonstrated that the Pickering emulsion method led to better dispersion of CNC in composites, resulting in improved tensile strength, flexibility, and thermal stability (compared with solvent-casted ones). In particular, the tensile strength increased by 20% and the crystallinity increased by 15% using the Pickering emulsion technique, indicating their potential as a new generation of sustainable packaging. The findings of this research could help in creating eco-friendly packaging options by improving the mechanical features of biodegradable composites and exploring potential alternatives to overcome their limitations.