We report significant intergrain magnetoresistance (IMR) in polycrystalline double perovskites of at room temperature. Systematics of the temperature dependence of IMR indicates that the observed large room-temperature IMR in originates from the ferrimagnetic nature of insulating grain boundaries as well as the half-metallicity of this perovskite. Our results indicate that a new avenue for spin-polarized tunneling junctions is to utilize insulating interface layers with ferromagnetic or ferrimagnetic coupling.
We have performed inelastic neutron scattering on a single crystal sample of to study the spin dynamics of the spin ladder layers and chains. Our data are best fitted with a dispersion which has a spin gap of and a maximum of , consistent with a coupling along the ladders, and a rung coupling . Excitations with an energy transfer of approximately 11.5 meV arise from a dimer chain with an antiferromagnetic intradimer coupling between next-nearest-neighbor Cu ions, and a ferromagnetic interdimer coupling . The dimer chains have a periodicity of five units.
Anisotropic electrical resistivity under high pressure was measured for a single crystal of , a hole-doped two-leg ladder compound. Superconductivity was observed between 3.5 and 8 GPa, accompanied by metallic resistivity between the ladders, which indicates semiconducting behavior at ambient pressure. This in turn strongly suggests that the application of pressure brings about a dimensional crossover from one to two, and that superconductivity in this system is a consequence of an insulator to superconductor transition in the anisotropic two-dimensional system.
We measured thermal conductivity , thermoelectric power , and electric conductivity of , showing an intricate interplay between metallic ferromagnetism (FM) and charge ordering (CO) instability. The change of , , and with temperature and agrees well with the effective medium theories for binary metal-insulator mixtures. This agreement clearly demonstrates that with the variation of as well as , the relative volumes of FM and CO phases drastically change and percolative metal-insulator transition occurs in the mixture of FM and CO domains.