This paper discusses a sustainable way to prepare construction materials from metallurgical slags. Steel slag, copper slag, lead-zinc slag, and electric furnace ferronickel slag are the most common metallurgical slags that could be used as supplementary cementitious materials (SCMs) and aggregates. However, they have some adverse effects that could significantly limit their applications when used in cement-based materials. The setting time is significantly delayed when steel slag is utilized as an SCM. With the addition of 30% steel slag, the initial setting time and final setting time are delayed by approximately 60% and 40%, respectively. Because the specific gravity of metallurgical slags is 10–40% higher than that of natural aggregates, metallurgical slags tend to promote segregation when utilized as aggregates. Furthermore, some metallurgical slags deteriorate the microstructure of hardened pastes, resulting in higher porosity, lower mechanical properties, and decreased durability. In terms of safety, there are issues with the soundness of steel slag, the alkali-silica reaction involving cement and electric furnace ferronickel slag, and the environmental safety concerns, due to the leaching of heavy metals from copper slag and lead-zinc slag.

Fly ash (FA) and ground granulated blast-furnace slag (GGBS) are the most widely used mineral admixtures in engineering. However, their roles in concrete under the equal strength grade, a common comparison method in engineering, were seldom reported. This study investigated the chloride ion permeability and drying shrinkage of concrete samples containing FA or GGBS under an equal strength grade. The samples’ strengths and slumps maintained the same levels by adjusting the water-to-binder ratios and superplasticizer dosages. The results show that both FA and GGBS can promote the resistance to chloride ion penetration and decrease the chloride diffusion coefficients, especially at late ages, due to the hydraulicity of GGBS and pozzolanic activity of FA. Compared with FA, GGBS presents a greater reduction in the concrete permeability due to its higher reactivity. Forty percent replacement levels of FA and GGBS can decrease the penetration level from “high” of plain cement concrete to “moderate” and “low”, respectively. In addition, FA and GGBS can decrease the drying shrinkage of concrete at high replacement levels (30% and 40%). This decrease is more significant in the FA-containing concrete, with the shrinkage decreasing from approximately 400 με to 350 με at a 40% replacement level. The findings can provide scientific guidance for applying FA and GGBS in practical engineering.