Spatial–temporal variation in soil organic carbon is an important factor for national targets to mitigate climate change and land degradation impacts. In this research, we took Guangdong Province of China as the study area, evaluated the spatial–temporal distributions of soil organic carbon using data from three China Geochemical Baseline projects (conducted in 2009, 2016, and 2023, respectively), and quantified the main driving factors of spatial–temporal variations in soil organic carbon using the random forest algorithm, further predicting the density and inventories of soil organic carbon. The results demonstrate that the mean value of SOC in Guangdong in 2009 was 0.81%; in 2016 it was 1.13%; and in 2023 it was 1.02%. The inventories of soil organic carbon (0–30 cm) in Guangdong Province were 0.61 Pg in 2009, 0.74 Pg in 2016, and 0.62 Pg in 2023. Soil in Guangdong acted as a carbon sink from 2009 to 2023 as a whole, and the most important driving force behind spatial–temporal variations in soil organic carbon was temperature, followed by precipitation and vegetation cover.

The environmental quality of the sediments in karst areas is a common concern, and it is of great significance to analyze the sources of the sediments. This study investigates the sources and its temporal variations of catchment sediments in a typical small karst watershed area. Toxic metal concentrations in the catchment area were monitored via three geochemical baseline projects in China. The sediment identification fingerprint tool (SIFT) was used to establish a geochemical model for tracing the main source contributions and its temporal variations of catchment sediments over the past 28 years (1992–2019). The catchment sediments in the small karst catchment area were mainly sourced from the background lithologies, among which limestone contributed the most, followed by dolomite, sand-shale, and mudstone; however, the anthropogenic lead–zinc tailings contributed the least. The contributions and temporal variations of each source were closely related to the lithology, topography, and landform, as well as the change in land-use and vegetation cover and the degree of rocky desertification. Moreover, the implementation of vegetation restoration and control of rocky desertification decreased the contributions of the upstream geological bodies, and the toxic metal content of the catchment sediment decreased accordingly. This study is of great significance for environmental governance in karst areas.