Copper oxide nanosheet-loaded zeolite 10X nanocomposites (CuO-zeolite NCs) were successfully prepared by modifying zeolite 10X with CuSO₄ aqueous solution. The formation of copper oxide nanosheets on the surface of zeolite 10X was observed by SEM. The thickness of CuO nanosheets was about 30–40 nm, and the width ranged from 200 nm to 300 nm. The XRD patterns showed that the new diffraction peaks of copper oxide appeared at 35.6° and 38.8°. According to the XPS results, the Cu 2p_3/2 and Cu 2p_1/2 peaks in CuO-zeolite NC were centered at 934.1 eV and 953.8 eV, which could be attributed to Cu(II). The EDS analysis revealed that the energy spectra of calcium gradually decreased as the copper ion concentration increased during the preparation of CuO-zeolite NCs. Meanwhile, the energy spectra of copper increased gradually, and the highest content of copper in CuO-zeolite NCs reached 22.35 wt.%. The BET surface areas of zeolite 10X and CuO-zeolite NCs were 587 and 363 m²/g, respectively, based on the N₂ adsorption–desorption experiment. The antibacterial activities of CuO-zeolite NC were evaluated using Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). The antibacterial activities were related to both copper ion content in CuO-zeolite NCs and the particle size of copper oxide. The results showed that nano CuO-loaded zeolite 10X inhibited the activity of E. coli and S. aureus. CuO-zeolite NCs are expected to be further used in antifouling coating.

We present a straightforward emulsion-induced interfacial anisotropic assembly method for in- situ synthesis of bowl-shaped, self-encapsulated mesoporous polydopamine (BMPDA) nanocontainers (M-M@P) loaded with 2-mercaptobenzimidazole (2-MBI). Results showed that the loading capacity of the bowl-shaped mesoporous polydopamine reaches 24 wt.%. The M-M@P exhibits a cumulative MBI release of 91.61% after immersion in a 3.5 wt.% NaCl solution at pH = 2 for 24 h, accompanied by a corrosion inhibition efficiency of 95.54%. Additionally, the acid-responsive M-M@P not only enables controlled release of MBI but also synergistically promotes the formation of a protective film on the carbon steel substrate via the chelation of PDA-Fe³⁺, thereby enhancing the self-healing performance of waterborne epoxy coatings.

Soil and water assessment tool (SWAT) model was used to calculate the runoff, nitrogen and phosphorus emissions in the Dagu River Basin from 2002 to 2012 and provided preliminary suggestions on environmental protection measures. Calibration on hydrological watershed parameters was obtained from data obtained from multiple representative stations. Cluster analysis was used to group all stations, and the parameters of different representative stations were applied to the entire geographical area to reflect the hydrological conditions of the basin. Additionally, the spatiotemporal changes and pollution source characteristics of nitrogen and phosphorus were analyzed. Anthropogenic sources—chemical fertilizer loss and livestock breeding—accounted for 49.9–29.6% of total nitrogen (TN) and 41.4% and 40.3% of total phosphorus (TP), respectively. Non-point sources accounted for 85.8% of the TN and 89.4% of the TP. Six landscape management practices were set up to evaluate the reduction effect on non-point source pollution loads, and comprehensive measures were proposed to reduce TN (TP) by ~ 70%. According to water quality model, the response relationship between river control and nutrient distribution in Jiaozhou Bay is calculated. Based on the findings, we propose an optimal control scheme for non-point source pollution in the Dagu River Basin and other similar basins.