The origins of natural hydrogen in natural gas systems of sedimentary basins and the capacity of these systems to store hydrogen remain inadequately understood, posing crucial questions for the large-scale exploration of natural hydrogen. This study reports on the natural gas composition, stable carbon and hydrogen isotopic values, and helium isotopic values of gas samples collected from the Qingshen gas deposit within volcanic rocks of the Songliao Basin. Natural hydrogen primarily originates from water radiolysis, water-rock interactions (WRI), and mantle. The Qingshen gas deposit contains 95.23 × 10 ⁹ cubic meters of abiotic CH ₄ , of which 15.24 × 10 ⁹ cubic meters was generated through hydrogen conversion via Fischer-Tropsch synthesis, with the maximum original hydrogen reserves calculated to be approximately 61.9 × 10 ⁹ cubic meters. We estimated that the study area has generated a maximum total of 572 × 10 ⁹ cubic meters of radiolytic hydrogen, 248 × 10 ⁹ cubic meters of WRI hydrogen, and 127 × 10 ⁹ cubic meters of mantle-derived hydrogen.

Although the productivity of modern volcanic soils is well established, the fertilization effects of ancient volcanic ash on aqueous ecosystems remains contentious. Here we demonstrate volcanic fertilization effects on a Late Triassic lacustrine ecosystem based on micropaleontological and geochemical records from the Yanchang Formation of North China. Frequent eruptions of a regional volcanic arc system increased cyanobacterial populations and organic carbon sinking fluxes, as recorded by extreme total organic carbon content (>30 wt.%) and positive organic carbon and negative nitrogen isotopic excursions. In turn, high levels of primary productivity induced intense water-column anoxia, facilitating preservation of organic matter. These findings underscore the potential influences of volcanism on ecological conditions, primary productivity, and carbon sequestration throughout geological history.

Paleokarst reservoirs are the major type of the Ordovician carbonate reservoirs in the Tahe Oilfield. Due to the strong heterogeneity in distribution, it is a real challenge to detect the spatial distribution of paleokarst reservoirs, especially those deeply buried more than 5500 m in the Tahe area. Based on the abundant core samples, this paper first described the structure of paleocaves drilled by well. Second, after time–depth conversions, the results from drilled wells were tied to three-dimensional (3D) seismic datasets, and then the threshold of host rocks and caves in wave impedance were identified. Third, the seismic-scale mapping and visualization of the paleokarst reservoirs were achieved by tracing the distribution of paleocaves. This approach was applied in the well T403 area, and the structure of the paleokarst, especially the runoff zone, was interpreted. 3D structure and spatial distribution of the paleokarst system was demonstrated by plane, vertical, and 3D models. Additionally, according to the hydrology genetic relationships, the paleocaves in the runoff zone were divided into sinkholes, main channel, and branch channel. The approach of a 3D geophysical characterization of a deeply buried paleokarst system can be applicable to Tahe and other similar paleokarst oilfields, which will guide hydrocarbon exploration in paleokarst reservoirs.