Tetrabutylammonium bromide (TBAB) is considered a promising alternative cold energy storage material. Due to the high dissociation heat of phase transition at an atmospheric pressure of 278–293 K, which reaches 200–500 kJ/kg, this substance is considered an effective cold energy storage medium for air conditioning systems. In this paper, the cold storage crystallization process of TBAB solution with different concentrations was tested by conducting experiments and the phase transition’s temperature and latent heat were measured. Finally, the growth characteristics of TBAB hydrate crystals with different concentrations (10%, 20%, 30% and 40%) were analyzed. Considering the cold storage temperature, phase transformation temperature and latent heat, the cold storage effect is the best when 40% TBAB solution is used. Although single substance phase change materials have a long service life, they have problems with low thermal conductivity and high undercooling. Therefore, researchers usually improve the performance of phase change materials by adding other auxiliary materials, thereby enhancing their application prospects. Among these auxiliary materials, adding nano additives to phase change materials can significantly improve latent heat, thermal conductivity and nucleation ability, while also reducing undercooling. Therefore, we studied the influence of different nano-additives (Al₂O₃, SiC, TiO₂ and ZnO) on phase change materials. The composites with excellent properties were screened by cooling step cooling curve and differential scanning calorimeter (DSC). Compared with pure TBAB solution, the phase transition latent heat of the composite phase change materials (PCMs) prepared by adding nanoparticles were significantly increased. The results show that adding nano-SiC into 40% TBAB solution can obtain better performance. This work not only provides reference for the further research, but also a sight to design the phase change materials for the application of new phase change cold storage materials.

A large number of bubbles generated by the air agitation device in an external melting ice storage system can cause the disturbance of the ice–water mixture, which can enhance the heat transfer and contribute to the reduction in energy consumption. The structural design and optimization of the air agitation device in an external melting ice storage system is the key issue for energy savings. In this study, the influence of different orifice spacings and diameters on the distribution of the gas–liquid flow field, gas holdup, heat-transfer coefficient, and power consumption in the ice storage tank was investigated by numerical simulation. The simulated results showed that the heat-transfer coefficient of the ice–water mixture with air bubbles should be 3–5 times higher than the natural convection when the air superficial velocity is 0.03 m/s. The gas holdup was mainly affected by the orifice spacing, and the maximum varied from 5.0% to 8.2%. When the orifice spacing was less than 150 mm, the gas holdup changed a little in the horizontal direction, and the uniformity became worse when the orifice spacing was larger than 180 mm. An orifice diameter larger than 3 mm can improve the heat transfer and cause less air-compressing energy consumption, which decreased by approximately 1.62%.

A water diffuser is a critical auxiliary equipment for an ice storage system during the external ice melting process. This paper proposes a linear multi-pore water diffuser for an ice storage system with 500 t of refrigeration capacity to enhance the performance of external ice melting. By establishing a three-dimensional two-phase volume of fluid (VOF) model, different structural designs of water diffusers for the ice storage device are numerically examined regarding the degree of turbulence, flow velocity, and pressure drop. The results show that the optimal water diffuser with five rows of trunk pipe and six perforated pores arranged in per row of branch pipe with a 4 mm diameter of perforated pores exhibiting a relatively lower degree of turbulence with a lower pressure drop compared with the other designs in this study. Meanwhile, the influence of the flow velocity on the ice melting process is also investigated by a numerical model of ice melting. It is found that the fed flow velocity from the main pipe inlet exhibits a great impact on the external ice melting process. Compared with the external ice melting process without the water diffuser, the external ice melting process with optimal water diffuser design under flow velocity of 1.0 m s⁻¹ could shorten the overall ice-melting time by 16 h. Additionally, through adjusting the water flow velocity, different output cooling can be realized to provide a fast response speed to the cooling variations in demand of the terminal users with a reduced cost.

Phase change materials (PCMs) are promising candidates for facilitating zero-energy thermal management on account of their constant phase-transition temperatures and excellent thermal storage capacity. However, low thermal conductivity, solid-state rigidity, and weak electromagnetic interference (EMI) shielding effectiveness are long-standing challenges limiting PCM-based wearable thermal regulation for portable flexible electronic devices. Herein, a Janus-type flexible phase change composite film is fabricated via a simple and low-cost phase inversion and direct spraying strategy, which incorporates an innovative combination of graphene nanoplatelets-cobalt nanoparticles@polyvinylidene fluoride (GNP-Co@PVDF) as the porous skeleton and MXene@polytannin acid (PTA) as the sprayed layer. Resultantly, the tailored flexible composite film achieves a 960% improvement on thermal conductivity relative to paraffin, coupled with prominent EMI-shielding performance of 38.9–62.5 dB and desirable enthalpy density of 146.9 J·g−1. Besides, this film also exhibits leakage-resistant property, multi-source-driven thermal responsiveness, shape memory feature, and robust cyclic stability. These integrated performances substantially broaden its application potential for advanced thermal management of smart portable electronics.

The encapsulation and heat conduction of molten salt are very important for its application in heat storage systems. The general practice is to solidify molten salt with ceramic substrate and enhance heat conduction with carbon materials, but the cycle stability is not ideal. For this reason, it is of practical significance to study heat storage materials with a carbon-free thermal conductive adsorption framework. In this paper, the in-situ reaction method was employed to synthetize the constant solid-state composites for high-temperature thermal energy storage. AlN is hydrolyzed and calcined to form h-Al₂O₃ with a mesoporous structure to prevent the leakage of molten eutectic salt at high temperature. Its excellent thermal conductivity simultaneously improves the thermal conductivity of the composites. It is found that 15CPCMs prepared with 15% water addition have the best thermal conductivity (4.928 W/m·K) and mechanical strength (30.2 MPa). The enthalpy and the thermal storage density of 15CPCMs are 201.4 J/g and 1113.6 J/g, respectively. Due to the excellent leak-proof ability and lack of carbon materials, the 15CPCMs can maintain almost no mass loss after 50 cycles. These results indicate that 15CPCMs have promising prospects in thermal storage applications.