Polymeric hydrogel actuators refer to intelligent stimuli‐responsive hydrogels that could reversibly deform upon the trigger of various external stimuli. They have thus aroused tremendous attention and shown promising applications in many fields including soft robots, artificial muscles, valves, and so on. After a brief introduction of the driving forces that contribute to the movement of living creatures, an overview of the design principles and development history of hydrogel actuators is provided, then the diverse anisotropic structures of hydrogel actuators are summarized, presenting the promising applications of hydrogel actuators, and highlighting the development of multifunctional hydrogel actuators. Finally, the existing challenges and future perspectives of this exciting field are discussed.

As one of the most outstanding materials, the analysis of the structure and function of hydrogels has been extensively carried out to tailor and adapt them to various fields of application. The high water content, which is beneficial for plenty of applications in the biomedical setting, prevents the adoption of hydrogels in flexible electronics and sensors in real life applications, because hydrogels lose their excellent properties, including conductivity, transparency, flexibility, etc., upon freezing at sub-zero temperatures. Therefore, depressing the liquid–solid phase transition temperature is a powerful means to expand the application scope of hydrogels, and will benefit the chemical engineering and materials science communities. This review summarizes the recent research progress of anti-freezing hydrogels. At first, approaches for the generation of anti-freezing (hydro)gels are introduced and their anti-freezing mechanisms and performances are briefly discussed. These approaches are either based on addition of salts, alcohols (cryoprotectants and organohydrogels), and ionic liquids (ionogels), modification of the polymer network or a combination of several techniques. Then, a concise overview of applications leveraged by the widened temperature resistance is provided and future research areas and developments are envisaged.

This tutorial review summarizes the recent advancement in various reversible crosslinks employed to construct supramolecular shape memory hydrogels (SSMHs) and different shape memory behaviors.

This review highlights the recent advances and discusses the challenges and perspectives of stimulus-responsive polymer (SRP)-based information-storage materials, which exhibit multi-mode or multi-level anti-counterfeiting performance.