High-efficiency production of xylene/trimethylbenzene from benzene/toluene with methanol is a potential way to promote the implementation on the coupled cycle development strategy of petrochemical and coal chemical industry and optimize the resource structure. At the same time, relying on the innovation of catalytic new materials, physical chemistry, intelligent capture technology, process engineering, and other principles and methods, p-xylene (PX) and trimethylbenzene (TMB) with higher added value were prepared by C_6-8~arene methylation, which could elevate the level of methylation field and improve the competitiveness of the industry. This paper focuses on the one-step methylation reaction of benzene with methanol or toluene with methanol to obtain high-purity p-xylene (BM-PX/TM-PX), and the one-step methylation reaction of xylene with methanol to obtain mesitylene (XM-TMB). The methylation reaction mechanism and the preparation strategy of a high-performance catalyst were reviewed. The high selectivity of PX obtained by precisely controlling the pore size and acid site distribution of zeolites was emphasized. Meanwhile, the current research progress of TMB, the kinetic/thermodynamics of the BM-PX/TM-PX, and XM-TMB methylation reaction were described. Based on a literature research and the conclusion of our research group, the mechanism of methylation reaction process was expounded. Finally, the new research direction of catalysts used and reaction process in methylation reaction were prospected in order to guide the rapid development of this field.

Furfural is one of the most important biomass platform compounds and can be used to prepare various high-value-added chemicals. The reactions of furfural with aliphatic alcohols via an oxidative esterification reaction or oxidative condensation reaction can bond two carbon molecules together and produce longer hydrocarbon chains chemicals, including methylfuroate and some low-volatility liquid biomass fuels. Thus, these reactions are considered significant utilization routes of furfural, and many inspiring catalytic systems have been designed to promoted these reactions. In this work, the reported catalytic systems for the oxidative esterification and oxidative condensation reactions are reviewed separately. The catalysts for the oxidative esterification reaction are reviewed for the classification of noble metal catalysts and non-noble metal catalysts, according to the active metals in the catalysts. For the oxidative condensation reactions, the studies using oxygen as the oxidant are reviewed firstly, and then the studies conducted using the hydrogen transfer process are analyzed subsequently. Furthermore, suggestions for future research directions for the oxidative esterification and oxidative condensation reactions are put forward.