We study experimentally how two key geometric parameters (pitch and gas fraction) of textured hydrophobic surfaces affect liquid slip. The two are independently controlled on precisely fabricated microstructures of posts and grates, and the slip length of water on each sample is measured using a rheometer system. The slip length increases linearly with the pitch but dramatically with the gas fraction above 90%, the latter trend being more pronounced on posts than on grates. Once the surfaces are designed for very large slips (), however, further increase is not obtained in regular practice because the meniscus loses its stability. By developing near-perfect samples that delay the transition from a dewetted (Cassie) to a wetted (Wenzel) state until near the theoretical limit, we achieve giant slip lengths, as large as .
Superhydrophobic (SHPo) surfaces have shown promise for passive drag reduction because their surface structures can hold a lubricating gas film between the solid surface and the liquid in contact with it. However, the types of SHPo surfaces that would produce any meaningful amount of reduction get wet under liquid pressure or at surface defects, both of which are unavoidable in the real world. In this Letter, we solve the above problem by (1) discovering surface structures that allow the restoration of a gas blanket from a wetted state while fully immersed underwater and (2) devising a self-controlled gas-generation mechanism that maintains the SHPo condition under high liquid pressures (tested up to 7 atm) as well as in the presence of surface defects, thus removing a fundamental barrier against the implementation of SHPo surfaces for drag reduction.
A gas in between micro- or nanostructures on a submerged superhydrophobic (SHPo) surface allows the liquid on the structures to flow with an effective slip. If large enough, this slippage may entail a drag reduction appreciable for many flow systems. However, the large discrepancies among the slippage levels reported in the literature have led to a widespread misunderstanding on the drag-reducing ability of SHPo surfaces. Today we know that the amount of slip, generally quantified with a slip length, is mainly determined by the structural features of SHPo surfaces, such as the pitch, solid fraction, and pattern type, and further affected by secondary factors, such as the state of the liquid–gas interface. Reviewing the experimental data of laminar flows in the literature comprehensively and comparing them with the theoretical predictions, we provide a global picture of the liquid slip on structured surfaces to assist in rational design of SHPo surfaces for drag reduction. Because the trapped gas, called plastron, vanishes along with its slippage effect in most application conditions, lastly we discuss the recent efforts to prevent its loss. This review is limited to laminar flows, for which the SHPo drag reduction is reasonably well understood.
The efficient water harvesting from air-laden moisture has been a subject of great interest to address world-wide water shortage issues. Recently, it has been shown that tailoring surface wettability can enhance the moisture harvesting performance. However, depending on the harvesting condition, a different conclusion has often been reported and it remains unclear what type of surface wettability would be desirable for the efficient water harvesting under the given condition. Here we compare the water harvesting performance of the surfaces with various wettability under two different harvesting conditions–dewing and fogging, and show that the different harvesting efficiency of each surface under these two conditions can be understood by considering the relative importance of the water capturing and removal efficiency of the surface. At fogging, the moisture harvesting performance is determined by the water removal efficiency of the surface with the oil-infused surfaces exhibiting the best performance. Meanwhile, at dewing, both the water capturing and removal efficiency are crucial to the harvesting performance. And well-wetting surfaces with a lower barrier to nucleation of condensates exhibit a better harvesting performance due to the increasing importance of the water capture efficiency over the water removal efficiency at dewing.