Nowadays, the use of hybrid structures and multi-component materials is gaining ground in the fields of environmental protection, water treatment and removal of organic pollutants. This study describes promising, cheap and photoactive self-supported hybrid membranes as a possible solution for wastewater treatment applications. In the course of this research work, the photocatalytic performance of titania nanowire (TiO₂ NW)-based hybrid membranes in the adsorption and degradation of methylene blue (MB) under UV irradiation was investigated. Characterization techniques such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), X-ray powder diffractometry (XRD) were used to study the morphology and surface of the as-prepared hybrid membranes. We tested the photocatalytic efficiency of the as-prepared membranes in decomposing methylene blue (MB) under UV light irradiation. The hybrid membranes achieved the removal of MB with a degradation efficiency of 90% in 60 min. The high efficiency can be attributed to the presence of binary components in the membrane that enhanced both the adsorption capability and the photocatalytic ability of the membranes. The results obtained suggest that multicomponent hybrid membranes could be promising candidates for future photocatalysis-based water treatment technologies that also take into account the principles of circular economy.

In the current research, surface-modified SiO₂ nanoparticles were used upon immersion in an applied base fluid (ethylene glycol:water = 1:1). The atomic layer deposition method (ALD) was introduced to obtain a thin layer of TiO₂ to cover the surface of SiO₂ particles. After the ALD modification, the TiO₂ content was monitored by energy dispersive X-ray spectroscopy (EDS). Transmission electron microscopy (TEM) and FT-IR spectroscopy were applied for the particle characterization. The nanofluids contained 0.5, 1.0, and 1.5 volume% solid particles and zeta potential measurements were examined in terms of colloid stability. A rotation viscosimeter and thermal conductivity analyzer were used to study the nanofluids’ rheological properties and thermal conductivity. These two parameters were investigated in the temperature range of 20 °C and 60 °C. Based on the results, the thin TiO₂ coating significant impacted these parameters.

Glassy carbon foam (GCF) catalyst supports were synthesized from waste polyurethane elastomers by impregnating them in sucrose solution followed by pyrolysis and activation (AC) using N₂ and CO₂ gas. The palladium nanoparticles were formed from Pd(NO₃)₂. The formed palladium nanoparticles are highly dispersive because the mean diameters are 8.0 ± 4.3 (Pd/GCF), 7.6 ± 4.2 (Pd/GCF-AC1) and 4.4 ± 1.6 nm (Pd/GCF-AC2). Oxidative post-treatment by CO₂ of the supports resulted in the formation of hydroxyl groups on the GCF surfaces, leading to a decrease in zeta potential. The decreased zeta potential increased the wettability of the GCF supports. This, and the interactions between –OH groups and Pd ions, decreased the particle size of palladium. The catalysts were tested in the hydrogenation of nitrobenzene. The non-treated, glassy-carbon-supported catalyst (Pd/GCF) resulted in a 99.2% aniline yield at 293 K and 50 bar hydrogen pressure, but the reaction was slightly slower than other catalysts. The catalysts on the post-treated (activated) supports showed higher catalytic activity and the rate of hydrogenation was higher. The maximum attained aniline selectivities were 99.0% (Pd/GCF-AC1) at 293 K and 98.0% (Pd/GCF-AC2) at 323 K.

Novel hybrid structures have attracted attention in several instances of scientific research and different technological applications in this decade due to their novel characteristics and wide range of applicability. Hybrid membranes with multiple components (three or more) are also increasingly used in water purification applications, and their ease of handling and reusability make them a promising candidate for the degradation of organic pollutants by photocatalysis. In this study, the preparation and characterization of tungsten trioxide nanowire (WO₃ NW)-based hybrid membrane structures are reported. Furthermore, the adsorption properties and photocatalytic efficiency of the as-prepared membranes against methylene blue (MB) organic dye under UV irradiation is also presented. Characterization techniques, such as scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray powder diffraction (XRD) are performed to study the morphology and surface of the as-prepared hybrid membranes. The removal efficiency of the hybrid membranes against MB is 77% in a 120 min decomposition reaction. The enhanced value can be attributed to the hybrid structure of the membrane that enhances not only the adsorption capability, but also the photocatalytic performance. Based on the results obtained, it is hoped that hybrid membrane technology could be a promising candidate for future photocatalysis-based water treatment applications.