The paper presents a comprehensive analysis of the elastic properties of polystyrene-based nanocomposites filled with different types of inclusions: small spherical particles (SiO₂ and Al₂O₃), alumosilicates (montmorillonite, halloysite natural tubules and mica), and carbon nanofillers (carbon black and multi-walled carbon nanotubes). Block samples of composites with different filler concentrations were fabricated by melt technology, and their linear and non-linear elastic properties were studied. The introduction of more rigid particles led to a more profound increase in the elastic modulus of a composite, with the highest rise of about 80% obtained with carbon fillers. Non-linear elastic moduli of composites were shown to be more sensitive to addition of filler particles to the polymer matrix than linear ones. A non-linearity modulus β_s comprising the combination of linear and non-linear elastic moduli of a material demonstrated considerable changes correlating with those of the Young’s modulus. The changes in non-linear elasticity of fabricated composites were compared with parameters of bulk non-linear strain waves propagating in them. Variations of wave velocity and decay decrement correlated with the observed enhancement of materials’ non-linearity.

Polypropylene fibers with fillers in the form of carbon nanoparticles of four types (technical carbon, graphitized carbon nanofibers, multi-walled carbon nanotubes, and single-walled carbon nanotubes) have been synthesized. For all types of fillers, the electrical conductivity of the fibers has been measured as a function of the concentration of nanoparticles and the percolation thresholds have been determined. A correlation between the nanoparticle concentration and the electrical conductivity of the percolation cluster at the percolation threshold with the cross section, the axial ratio, and the shape of the nanoparticles dispersed in the polymer matrix has been discussed. The dependence of the electrical conductivity of the composite material with carbon nanofibers on the temperature has been measured.

The lack of suitable functional groups for cell adhesion on the surface of Polycaprolactone (PCL) is one of the main limitations in order to use PCL for biomedical applications. The aim of this research is to modify the PCL film surface using arginine, via an aminolysis reaction. In this regard, after PCL films formation by casting method, they were immersed in arginine solutions of various concentration at room temperature or then heated to 40 °C and in the presence of isopropanol or without it. To assess the structure of the modified surface, its wettability, and mechanical properties, methods of measuring the contact angle and the strip tensile test were used, and to compare the degree of attachment and the rate of cell proliferation, the method of fluorescent staining of cultured cells was used. The change in protein synthesis by cells on the modified surface was assessed using Western blotting. The results obtained show that the treatment of PCL films with an aqueous solution of arginine at room temperature for 1 day increases the hydrophilicity of the surface. Wherein surface modification led to a two-fold decrease of mechanical strength and flow stress, but elongation increase by about 30% for PCL films after modification in 0.5 M aqueous arginine solution at room temperature. Moreover, cell attachment and proliferation, as well as collagen synthesis, were significantly enhanced after arginine modification. The proposed simple and effective method for modifying PCL films with arginine significantly expands the possibilities for developing biocompatible scaffolds for tissue engineering.

Numerous studies have been performed on different aspects of the mechanical behavior of polymer nanocomposites; however, the results obtained still lack a comprehensive comparative analysis of the mechanical properties of composites containing nanofillers of different shapes and concentrations and subjected to different static and dynamic loads. Carbon nanofillers were shown to provide the most significant improvement in the elastic properties of polymer composites. In this paper, we present a comparative analysis of the mechanical properties of polystyrene-based nanocomposites filled with carbon allotropes of different shapes: spherical fullerene particles, filamentary multi-walled nanotubes, and graphene platelets, fabricated by the same technology. The influence of shape and concentration of dispersed carbon fillers on mechanical and viscoelastic properties of composites in different stress–strain states was evaluated based on the results of tensile and three-point bending tests, and ultrasonic and dynamic mechanical analysis. Comparison of the static and dynamic elastic properties of nanocomposites allowed us to analyze their variations with frequency. At low concentrations of 0.1 wt% and 0.5 wt% all nanofillers did not provide significant improvement of elastic characteristics of composites. More efficient reinforcement was observed at the concentration of 5 wt%. Among the filler types, some increase in composite rigidity was observed with the addition of filamentary particles. The introduction of the layered filler provided the most pronounced rise in the composite rigidity. The weak frequency dependence of the mechanical loss tangent, which is characteristic of amorphous thermoplastics, was demonstrated for all the samples.

A method for preparing laboratory samples of fibers from glycolide-co-D,L-lactide to produce bioresorbing suture filaments with a controlled complex of properties is developed. The morphology of fibers obtained through melt spinning is studied. The peculiarities of the mechanical properties of fibers are investigated.