Conserving clean and safe freshwater is a global challenge, with nitrogen (N) and phosphorus (P) as frequent limiting factors affecting water quality due to eutrophication. This paper provides a critical overview of the spatiotemporal variability in both nutrient concentrations and their total mass ratio (TN:TP) in the canal network of the Hydro system Danube–Tisza–Danube at 21 measuring locations monitored by the Environmental Protection Agency of the Republic of Serbia over a length of almost 1000 km, collected once a month during the last decade. A spatiotemporal variation in nutrient concentrations in the tested surface water samples was confirmed by correlations and cluster analyses. The highest TN concentrations were found in winter and early spring (non-vegetation season), and the highest TP concentrations in the middle of the year (vegetation season). The TN:TP mass ratio as an indicator of the eutrophication pointed out N and P co-limitation (TN:TP 8–24) in 64% of samples, N limitation (TN:TP < 8) was detected in 27% and P limitation (TN:TP > 24) in the remaining 9% of water samples. Such observations indicate slow-flowing, lowland water courses exposed to the effects of non-point and point contamination sources as nutrient runoff from the surrounding farmlands and/or urban and industrial zones, but further investigation is needed for clarification. These results are an important starting point for reducing N and P runoff loads and controlling source pollution to improve water quality and underpin recovery from eutrophication in the studied watershed.

To test an assumption that organic soil can ameliorate nutritional disorders associated with metal and salinity stresses, we exposed salt-sensitive strawberry and lettuce to four salinity (0–60 mM NaCl) and three contamination (0.3–5 mg Cd/kg) rates in peat (pH_H2O = 5.5). The results showed that, even at 20 mM NaCl, salinity stress exerted a dominant effect on rhizosphere biogeochemistry and physiological processes, inducing leaf-edge burns, chlorosis/necrosis, reducing vegetative growth in crops; at ≥40 mM, NaCl mortality was induced in strawberry. Signifiacntly decreased K/Na, Ca/Na and Mg/Na concentration ratios with raising salinity were confirmed in all tissues. The combined CdxNaCl stresses (vs. control) increased leaf Cd accumulation (up to 42-fold in lettuce and 23-fold in strawberry), whereas NaCl salinity increased the accumulation of Zn (>1.5-fold) and Cu (up to 1.2-fold) in leaves. Lettuce accumulated the toxic Cd concentration (up to 12.6 mg/kg) in leaves, suggesting the strong root-to-shoot transport of Cd. In strawberry Cd, concentration was similar (and sub-toxic) in fruits and leaves, 2.28 and 1.86 mg/kg, respectively, suggesting lower Cd root-to-shoot translocation, and similar Cd mobility in the xylem and phloem. Additionally, the accumulation of Cd in strawberry fruits was exacerbated at high NaCl exposure (60 mM) compared with lower NaCl concentrations. Thus, in salinized, slightly acidic and organically rich rhizosphere, pronounced organo- and/or chloro-complexation likely shifted metal biogeochemistry toward increased mobility and phytoavailability (with metal adsorption restricted due to Na⁺ oversaturation of the caton exchange complex in the substrate), confirming the importance of quality water and soils in avoiding abiotic stresses and producing non-contaminated food.