The structural evolution and sedimentary differentiation of the Sichuan Basin in China are complex, with intricate reservoir pore structures that significantly impact shale gas production. This study examines the complexity and heterogeneity of the microscopic pore structures in the deep marine shale reservoir in the Longmaxi Formation. Pore structure characterization techniques are used to compare deep and shallow–medium marine shales, and siliceous and silty shales. The results reveal the factors influencing pore structure and their impact on exploration and development. The key points are as follows: (1) The pore structure of deep siliceous shale is the most complex due to its diverse range of pore development patterns, pore types, and sizes. (2) The box dimension of full pore size is about 1.52 for deep marine shale and 1.46 for shallow–medium shale. Organic matter (OM) content, the degree of pore development, and inorganic mineral content all correlate positively with the complexity of the pore structure in deep marine shale, which affects the formation of high-quality reservoirs. (3) Lateral heterogeneity of pore structures shows strong regional variations in the study area. Heterogeneity is more pronounced in the deep marine shale than in the medium and shallow shale formations. OM mesopores significantly influence the overall heterogeneity of the shale pore system. The deep marine shale reservoir is situated in an area with strong regional variations. The pore structure of high-quality reservoirs is more complex than those of shallow–medium marine shales, displaying notable heterogeneity. Pore structures with fractal dimension values close to that of the shallow–medium formations (box dimensions within 1.5) offer promising targets for the exploration and development of deep marine shale gas.

Shale pore systems are the result of the geological evolution of different matrix assemblages, and the composition of gas shale is considered to affect the pore systems in shale reservoirs. This study aimed to investigate the impact of both organic and inorganic constituents on the shale pore system, including specific surface area (SSA) and pore volume in Wufeng–Longmaxi Shale. Multiple linear regression (MLR) was employed to examine the contributions of different components to shale pore structure. The pore structure parameters, including pore SSA and pore volume, were obtained by gas adsorption experiments in 32 Wufeng–Longmaxi Shale (Late Ordovician–Early Silurian) samples. Both pore SSA and pore volume were calculated by the density functional theory (DFT) model on shale samples, and the pore types were determined by high-resolution field emission scanning electron microscopy (FE-SEM). The results of the X-ray diffractometer (XRD) analysis indicate that the Wufeng–Longmaxi Shale is dominated by quartz, clays, carbonates, feldspar, pyrite, and organic matter. Four models were made using SPSS software, all of which showed significant correlation between shale pore size and organic matter (OM) and clays. The content of organic matter played the biggest role in determining the size and structure of the pores. Although the content of quartz is the highest and serves as a rigid skeleton in shale reservoirs, it has complicated effects on the pore structure. In this study, most of the quartz is biogenetic and part of it is transformed from clays in deep shale. Therefore, these two parts of quartz are, respectively, related to organic matter and clays. In essence, the pores related to these two parts of quartz should be attributed to organic matter and clays, which also support the conclusion of the MLR models.

The marine shale of the Upper Ordovician Wufeng Formation–Lower Silurian Longmaxi Formation is the main source rock and the target of shale gas exploration in the southern Sichuan Basin. The maturity of organic matter (OM) is a vital indicator for source rock evaluation. Due to the lack of vitrinite, the organic matter maturity of the Wufeng–Longmaxi Formations in the southern Sichuan Basin is difficult to accurately evaluate. In total, 33 core samples of the Wufeng–Longmaxi Formations in the southern Sichuan Basin were selected to observe the optical characteristics of solid bitumen and graptolites and measure their random reflectance. Simultaneously, Raman spectroscopic parameters of kerogen were also used to quantitatively analyze the change in maturity. By using Raman spectroscopic parameters as mediators, conversion equations between graptolite random reflectance (GR_or) and equivalent vitrinite reflectance (EqVR_o) were established. Taking the calculation results of EqVR_o as constraints, the tectono-thermal evolution history of Wufeng–Longmaxi Shale in the southern Sichuan Basin is constructed through basin modelling. The results show that the maturity of Wufeng–Longmaxi Shale in the western Changning, Luzhou-western Chongqing, eastern Changning and Weiyuan areas decreases successively. The EqVR_o falls in the ranges of 3.61%~3.91%, 2.92%~3.57%, 3.08%~3.25%, 2.41%~3.12%, and the average EqVR_o is 3.73%, 3.30%, 3.18% and 2.80%, respectively. Thermal evolution in western Changning was controlled by the thermal effect of the Emeishan mantle plume and paleo-burial depth, while the thermal evolution of other areas was mainly controlled by paleo-burial depth. This study provides a reliable parameter for the evaluation of thermal maturity and makes a more accurate calibration of the maturity of the Wufeng–Longmaxi Formations in the southern Sichuan Basin; it also expounds the factors for the differences in thermal evolution in different parts of the area.

Hydrothermal dolomite paleokarst reservoir is a type of porous carbonate reservoir, which has a secondary porosity and can store a large amount of oil and gas underground. The reservoir is formed by magnesium-rich hydrothermal fluids during the karstification and later stages of the transformation. Due to the strong heterogeneity and thin thickness of hydrothermal dolomite paleokarst reservoirs, it is a real challenge to characterize the spatial distribution of the reservoirs. In this paper, we studied the hydrothermal dolomite paleokarst reservoir in the Wolonghe gasfield of the eastern Sichuan Basin. First, based on detailed observations of core samples, the characteristics and storage space types of the dolomite reservoir were described. Secondly, the petrophysical parameters of the paleokarst reservoirs were analyzed, and then the indicator factor for the dolomite reservoirs was established. Thirdly, using the time–depth conversion method, the geological characteristics near boreholes were connected with a three-dimensional (3D) seismic dataset. Several petrophysical parameters were predicted by prestack synchronous inversion technology, including the P-wave velocity, S-wave velocity, P-wave impedance, and the hydrothermal dolomite paleokarst reservoir indicator factor. Finally, the hydrothermal dolomite paleokarst reservoirs were quantitatively predicted, and their distribution model was built. The 3D geophysical characterization approach improves our understanding of hydrothermal dolomite paleokarst reservoirs, and can also be applied to other similar heterogeneous reservoirs.

Shale in the Wufeng Formation of the upper Ordovician and Longmaxi Formation of lower Silurian in the Sichuan Basin and its surrounding area is widespread. Shale gas resources are abundant. Shale gas in the Wufeng Formation and the Longmaxi Formation in the basin has been a major breakthrough. The basin margin transition zone in southeastern Chongqing is in an intense tectonic activity area, which is more complicated and special than the stable stratum in the basin. Therefore, it is necessary to put forward higher requirements for preservation conditions and enrichment pattern evaluation of shale gas. Therefore, in view of the complicated structural pattern of the basin margin transition zone in southeastern Chongqing, the preservation conditions and reservoir forming patterns are analyzed through structural evolution, uplift and denudation, fault development, structural styles, roof and floor conditions, and formation pressure. The results show that the main reason for the formation of normal pressure is the late uplift, denudation and fault development. The pressure coefficient from the basin to the outer layer is changed from overpressure to normal pressure, and structural transformation forms the preservation form of shale gas with narrow and steep residual anticline, wide residual syncline and residual slope. The preservation condition evaluation of normal shale gas should be based on structural factors such as structural evolution, structural style, uplift and denudation degree and fault development degree, with formation pressure coefficient as reference condition, combined with material basic conditions such as roof and floor conditions and formation thickness. The findings of this study can help for better understanding of the “sweet spot” prediction of normal pressure shale gas in complex structural area.