A novel Bi 2 MoO 6 –MIL-100(Fe) photocatalyst was synthesized by a facile solvothermal method for the first time, and characterized by XRD, SEM, XPS, UV-vis, TEM, and PL. The Bi 2 MoO 6 –MIL-100(Fe) exhibited excellent photocatalytic activity and stability.