David Rafaja

Prof. David Rafaja

Institute of Materials Science, Technische Universität Bergakademie Freiberg, Freiberg, Germany
orcid

Research Focus & Metrics

Academic Career Length

38Years (1989-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

View All Publications
3 December 2014 in Metallurgical and Materials Transactions A
Verified
Journal Article
Closed access
PDF file
SMStefan Martin
Stefan Martin
SWSteffen Wolf
Steffen Wolf
UMUlrich Martin
Ulrich Martin
LKLutz Krüger
Lutz Krüger
David RafajaDavid Rafaja
David Rafaja

22 October 2001 in Physical Review B
Verified
Journal Article
Closed access
PDF file
JPJ. Petzelt
J. Petzelt
TOT. Ostapchuk
T. Ostapchuk
IGI. Gregora
I. Gregora
IRI. Rychetský
I. Rychetský
SHSusanne Hoffmann-Eifert
Susanne Hoffmann-Eifert
RWR. Waser
R. Waser
Thorough Raman and infrared (IR) reflectivity investigations of nominally pure SrTiO3 ceramics in the 10–300 K range have revealed a clear presence of the polar phase whose manifestation steeply increases on cooling. The Raman strengths of the Raman-forbidden IR modes are proportional to ωTO1−α(α≈1.6) where ωTO1 is the polar soft mode frequency. No pronounced permittivity dispersion is observed below the soft mode frequency so that, as in single crystals, the static permittivity is essentially determined by the soft mode contribution. A theory is suggested which assumes a frozen dipole moment connected with the grain boundaries which induces the polar phase in the grain bulk in correlation with the bulk soft-mode frequency. This stiffens slightly the effective soft mode response and reduces the low-temperature permittivity compared to that of single crystals. Moreover, the polar soft mode strongly couples to the Eg component of the structural soft doublet showing that the polar axis is perpendicular to the tetragonal axis below the structural transition which is shifted to 132 K in our ceramics. Whereas the TiO6 octahedra tilt (primary order parameter) below the structural transition corresponds to that in single crystals, much smaller A1g−Eg splitting of the structural soft doublet shows that the tetragonal deformation (secondary order parameter) is nearly 10 times smaller, apparently due to the grain volume clamping in ceramics.

1 January 1998 in Journal of Alloys and Compounds
Verified
Journal Article
Closed access
CKC. Kral
C. Kral
Walter LengauerWalter Lengauer
Walter Lengauer
David RafajaDavid Rafaja
David Rafaja
PEP. Ettmayer
P. Ettmayer

1 November 1994 in Journal of Alloys and Compounds
Verified
Journal Article
Closed access
KAK. Aigner
K. Aigner
Walter LengauerWalter Lengauer
Walter Lengauer
David RafajaDavid Rafaja
David Rafaja
PEP. Ettmayer
P. Ettmayer

1 February 2002 in Wear
Verified
Journal Article
Closed access
PFPeter Filip
Peter Filip
ZWZdenek Weiss
Zdenek Weiss
David RafajaDavid Rafaja
David Rafaja

1 February 2018 in Acta Materialia
Verified
Journal Article
Closed access
AKA.R. Kilmametov
A.R. Kilmametov
YIYu. Ivanisenko
Yu. Ivanisenko
AMA.A. Mazilkin
A.A. Mazilkin
BSB.B. Straumal
B.B. Straumal
AGA.S. Gornakova
A.S. Gornakova
HHH. Hahn
H. Hahn