Transmission of planar layers of cholesteric liquid crystals is studied in pulsed electric fields perpendicular to the helix axis at normal incidence of both linearly polarized and unpolarized light. Spectral and light polarization properties of the primary photonic band and the field-induced bands up to fourth order of Bragg selective reflection are studied in detail. In our experiments we have achieved an electric field strength several times higher than the theoretical values corresponding to the critical field of full helix unwinding. However, the experiments show that despite the high strength of the electric field applied the helix does not unwind, but strongly deforms, keeping its initial spatial period. Strong helix deformation results in distinct spectral band splitting, as well as very high field-induced selective reflectance that can be applied in lasers and other optoelectronic devices. Peculiarities of inducing and splitting the bands are discussed in terms of the scattering coefficient approach. All observed effects are confirmed by numerical simulations. The simulations also show that liquid crystal surface anchoring is not the factor that prevents the helix unwinding. Thus, the currently acknowledged concept of continuous helix unwinding in the electric field should be reconsidered.

Background: The alignment of liquid crystals by surfaces is crucial for applications. It determines the director configuration in the bulk, its stability against defects and electro-optical switching scenarios. The conventional planar alignment of rubbed polymer layers can be locally flipped to vertical by irradiation with a focused ion beam on a scale of tens of nanometers.Results: We propose a digital method to precisely steer the liquid crystal director tilt at polymer surfaces by combining micrometer-size areas treated with focused ion beam and pristine areas. The liquid crystal tends to average the competing vertical and planar alignment actions and is stabilized with an intermediate pretilt angle determined by the local pattern duty factor. In particular, we create micrometer-sized periodic stripe patterns with this factor gradually varying from 0 to 1. Our optical studies confirm a predictable alignment of a nematic liquid crystal with the pretilt angle continuously changing from 0° to 90°. A one-constant model neglecting the difference between the elastic moduli reproduces the results quantitatively correctly.Conclusion: The possibility of nanofabrication of polymer substrates supporting an arbitrary (from planar to vertical) spatially inhomogeneous liquid crystal alignment opens up prospects of “imprinting” electrically tunable versatile metasurfaces constituting lenses, prisms and q-plates.

The field-induced orientational transition in layers of cholesteric liquid crystals with spatially periodic modulation of the surface anchoring is studied by numerical simulations and experimentally. The modulation of the surface anchoring is implemented using high-resolution focused ion-beam treatment of a polymer film providing planar alignment conditions. A specific feature of the orientational transition is that the thermodynamically stable initial planar structure with the helix axis along the normal to the layer transforms under an electric field into an equilibrium structure with a deformed lying helix (DLH) in the plane of the layer. For such a transition to occur the natural pitch of the cholesteric helix must be substantially less than the anchoring modulation period. The appearance of the DLH with a pitch corresponding to the anchoring modulation period results in strongly enhanced first-order diffraction efficiency. The orientational DLH transition is characterised by a rather narrow driving voltage range with a pronounced hysteresis. The waveguide lasing effect with characteristic of the deformed helix spectral modes is demonstrated in a range of the DLH transition.

Liquid crystals self‐assemble on nanopatterned alignment layers into purely soft matter metasurfaces sensitive to external stimuli and imparting tailored spatial modulations to transmitted light wavefronts. Upon fine optimization, they are capable of efficient light deflection by virtue of anomalous refraction into a dominating transmission diffraction order. To expand the spectral range and acquire additional functionality, we put forward the double‐sided metasurface design based on the liquid crystal alignment by a pair of complementing patterned substrates. We numerically optimize, fabricate, and experimentally characterize metasurfaces refracting red light with an efficiency of up to 70% and sustaining the efficiency above 50% in a broad range of visible wavelengths exceeding 500 nm. We verify that the refraction is reversibly switched in less than 10 ms by voltages of a few volts. We also report on a remarkable mechanical reconfigurability, as micrometer‐scale relative substrate shift flips the refraction direction.

We demonstrate field-induced 2D-photonic liquid crystals (LC). The 2D spatially periodic modulation of the LC director field is achieved using a geometry with two crossed interdigitated systems of electrodes located at opposite sides of the LC layer. With a special method of dual-field driving, a very fast switching between different spatially periodic LC director distributions is achieved. The director field distribution and potential use of these photonic crystals for fast switched multidirectional lasing is discussed.