Biomass burning releases trace gases and aerosol particles that significantly affect the composition and chemistry of the atmosphere. Australia contributes approximately 8% of gross global carbon emissions from biomass burning, yet there are few previous measurements of emissions from Australian forest fires available in the literature. This paper describes the results of field measurements of trace gases emitted during hazard reduction burns in Australian temperate forests using open-path Fourier transform infrared spectroscopy. In a companion paper, similar techniques are used to characterise the emissions from hazard reduction burns in the savanna regions of the Northern Territory. Details of the experimental methods are explained, including both the measurement set-up and the analysis techniques employed. The advantages and disadvantages of different ways to estimate whole-fire emission factors are discussed and a measurement uncertainty budget is developed. Emission factors for Australian temperate forest fires are measured locally for the first time for many trace gases. Where ecosystem-relevant data are required, we recommend the following emission factors for Australian temperate forest fires (in grams of gas emitted per kilogram of dry fuel burned) which are our mean measured values: 1620 ± 160 g kg⁻¹ of carbon dioxide; 120 ± 20 g kg⁻¹ of carbon monoxide; 3.6 ± 1.1 g kg⁻¹ of methane; 1.3 ± 0.3 g kg⁻¹ of ethylene; 1.7 ± 0.4 g kg⁻¹ of formaldehyde; 2.4 ± 1.2 g kg⁻¹ of methanol; 3.8 ± 1.3 g kg⁻¹ of acetic acid; 0.4 ± 0.2 g kg⁻¹ of formic acid; 1.6 ± 0.6 g kg⁻¹ of ammonia; 0.15 ± 0.09 g kg⁻¹ of nitrous oxide and 0.5 ± 0.2 g kg⁻¹ of ethane.

When compared to established point-sampling methods, Open-Path Fourier Transform Infrared (OP-FTIR) spectroscopy can provide path-integrated concentrations of multiple gases simultaneously, in situ and near-continuously. The trace gas pathlength amounts can be retrieved from the measured IR spectra using a forward model coupled to a non-linear least squares fitting procedure, without requiring "background" spectral measurements unaffected by the gases of interest. However, few studies have investigated the accuracy of such retrievals for CO₂, CH₄ and CO, particularly across broad concentration ranges covering those characteristic of ambient to highly polluted air (e.g. from biomass burning or industrial plumes). Here we perform such an assessment using data collected by a field-portable FTIR spectrometer. The FTIR was positioned to view a fixed IR source placed at the other end of an IR-transparent cell filled with the gases of interest, whose target concentrations were varied by more than two orders of magnitude. Retrievals made using the model are complicated by absorption line pressure broadening, the effects of temperature on absorption band shape, and by convolution of the gas absorption lines and the instrument line shape (ILS). Despite this, with careful model parameterisation (i.e. the optimum wavenumber range, ILS, and assumed gas temperature and pressure for the retrieval), concentrations for all target gases were able to be retrieved to within 5%. Sensitivity to the aforementioned model inputs was also investigated. CO retrievals were shown to be most sensitive to the ILS (a function of the assumed instrument field-of-view), which is due to the narrow nature of CO absorption lines and their consequent sensitivity to convolution with the ILS. Conversely, CO₂ retrievals were most sensitive to assumed atmospheric parameters, particularly gas temperature. Our findings provide confidence that FTIR-derived trace gas retrievals of CO₂, CH₄ and CO based on modeling can yield results with high accuracies, even over very large (many order of magnitude) concentration ranges that can prove difficult to retrieve via standard classical least squares (CLS) techniques. With the methods employed here, we suggest that errors in the retrieved trace gas concentrations should remain well below 10%, even with the uncertainties in atmospheric pressure and temperature that might arise when studying plumes in more difficult field situations (e.g. at uncertain altitudes or temperatures).

Drained peatlands are significant hotspots of carbon dioxide (CO₂) emissions and may also be more vulnerable to fire with its associated gaseous emissions. Under the United Nations Framework Convention on Climate Change (UNFCCC) and the Kyoto Protocol, greenhouse gas (GHG) emissions from peatlands managed for extraction are reported on an annual basis. However, the Tier 1 (default) emission factors (EFs) provided in the IPCC 2013 Wetlands Supplement for this land use category may not be representative in all cases and countries are encouraged to move to higher-tier reporting levels with reduced uncertainty levels based on country- or regional-specific data. In this study, we quantified (1) CO₂-C emissions from nine peat extraction sites in the Republic of Ireland and the United Kingdom, which were initially disaggregated by land use type (industrial versus domestic peat extraction), and (2) a range of GHGs that are released to the atmosphere with the burning of peat. Drainage-related methane (CH₄) and nitrous oxide (N₂O) emissions as well as CO₂-C emissions associated with the off-site decomposition of horticultural peat were not included here. Our results show that net CO₂-C emissions were strongly controlled by soil temperature at the industrial sites (bare peat) and by soil temperature and leaf area index at the vegetated domestic sites. Our derived EFs of 1.70 (±0.47) and 1.64 (±0.44) t CO₂-C ha⁻¹ yr⁻¹ for the industrial and domestic sites respectively are considerably lower than the Tier 1 EF (2.8 ± 1.7 t CO₂-C ha⁻¹ yr⁻¹) provided in the Wetlands Supplement. We propose that the difference between our derived values and the Wetlands Supplement value is due to differences in peat quality and, consequently, decomposition rates. Emissions from burning of the peat (g kg⁻¹ dry fuel burned) were estimated to be approximately 1346 CO₂, 8.35 methane (CH₄), 218 carbon monoxide (CO), 1.53 ethane (C₂H₆), 1.74 ethylene (C₂H₄), 0.60 methanol (CH₃OH), 2.21 hydrogen cyanide (HCN) and 0.73 ammonia (NH₃), and this emphasises the importance of understanding the full suite of trace gas emissions from biomass burning. Our results highlight the importance of generating reliable Tier 2 values for different regions and land use categories. Furthermore, given that the IPCC Tier 1 EF was only based on 20 sites (all from Canada and Fennoscandia), we suggest that data from another 9 sites significantly expand the global data set, as well as adding a new region.

Airborne Light Detection and Ranging (LiDAR) is a survey tool with many applications in forestry and forest research. It can capture the 3D structure of vegetation and topography quickly and accurately over thousands of hectares of forest. However, very few studies have assessed how accurately LiDAR can measure surface topography under forest canopies, which may be important, for example, in relation to analysis of pre- and post-burn surface height maps used to quantify the combustion of organic soils. Here, we use ground survey equipment to assess digital terrain model (DTM) accuracy in a deciduous broadleaf forest, during both leaf-on and leaf-off conditions. Using the leaf-on LiDAR dataset we quantitatively assess vertical vegetation structure, and use this as a categorical explanatory variable for DTM accuracy. In the presence of leaf-on vegetation, DTM accuracy is severely reduced, with low-stature undergrowth vegetation (such as ferns) causing the greatest errors (RMSE > 1 m). Errors are lower under leaf-off conditions (RMSE = 0.22 m), but still of a magnitude similar to that reported for mean depths of burn in fires involving organic soils. We highlight the need for adequate ground control schemes to accompany any forest-based airborne LiDAR survey which require highly accurate DTMs.

We characterised trace gas emissions from Australian temperate forest fires through a mixture of open-path Fourier transform infrared (OP-FTIR) measurements and selective ion flow tube mass spectrometry (SIFT-MS) and White cell FTIR analysis of grab samples. We report emission factors for a total of 25 trace gas species measured in smoke from nine prescribed fires. We find significant dependence on modified combustion efficiency (MCE) for some species, although regional differences indicate that the use of MCE as a proxy may be limited. We also find that the fire-integrated MCE values derived from our in situ on-the-ground open-path measurements are not significantly different from those reported for airborne measurements of smoke from fires in the same ecosystem. We then compare our average emission factors to those measured for temperate forest fires elsewhere (North America) and for fires in another dominant Australian ecosystem (savanna) and find significant differences in both cases. Indeed, we find that although the emission factors of some species agree within 20 %, including those of hydrogen cyanide, ethene, methanol, formaldehyde and 1,3-butadiene, others, such as acetic acid, ethanol, monoterpenes, ammonia, acetonitrile and pyrrole, differ by a factor of 2 or more. This indicates that the use of ecosystem-specific emission factors is warranted for applications involving emissions from Australian forest fires.