Stormwater runoff monitoring was carried out from 2011 to 2015 to investigate the relationships between rainfall conditions (antecedent dry days (ADDs), rainfall intensity, depth and duration), and water quality parameters of stormwater from a paved road in Korea. Factor analysis suggested that the effect of rainfall conditions on the concentrations of selected pollutants varied depending on the pollutant. As total COD (total chemical oxygen demand) concentration increased, the level of heavy metals increased and resulted in a decrease of BOD5 (biochemical oxygen demand) because of their toxicity. In addition, ADDs had a significant impact on the wash-off of solids from paved road. The predominant particles in stormwater were 30 μm and smaller, and increased in concentration as ADDs increased. Thus, the initial load of accumulated particles became a major factor in the wash-off process. The mass of particle-related pollutants was also subject to the effect of ADDs due to the affinity between pollutants and predominant particles (<30 μm). However, the effect of ADDs on the mass of organic matter and nitrogen was relatively weak. ADDs contributed to the decrease of some pollutants by photo-oxidation, volatilization and natural decay over dry days, as well as desorption from solids during rainfall.
29 August 2022 in Science of The Total Environment
A 0.23-ha pilot wetland was constructed to examine its effectiveness for the control of nonpoint source pollution (NPS) from a 7.42-ha agricultural watershed in Korea. This research emphasised the removal patterns of particulate and dissolved forms of pollutants on both dry (base flow) and wet days (storm flow). The hydraulic loading rates were high on rainy days, with an average value of 0.78 m/day, but around 0.08 m/day on dry days. Particulate forms of pollutants, such as TSS, COD and TP, were removed to a greater extent on wet days due to sedimentation. On wet days, the incoming concentrations of NH4-N and soluble reactive phosphorus (SRP) were higher than during dry days, and can be partly retained via filtration and adsorption as they go through the wetland. The retention of TP and TSS on dry days could be affected by short antecedent dry days (ADDs), which will cause frequent hydraulic fluctuations in the wetland. Nitrogen removal is not influenced by this condition, with an average retention of around 20% on dry days, higher than the 6% removal on wet days.
The performance of three pumice-woodchip packed stormwater biofilter (PWSWBF) systems with three packing volume ratios of pumice to woodchip (1:2, 1:1 and 2:1) were compared. The results show that the PWSWBF system packed with a lower percentage of woodchip attained a higher removal efficiency of TCOD, TN, NH4–N and TP, whereas all three systems completely removed nitrate. The highest removal efficiencies for TCOD, TN, NH4–N, NO3–N and TP were 95%, 70%, 86%, 100% and 100%, respectively. In the biofilter with a lower percentage of woodchip, the pollutants that get removed through aerobic biological processes were removed more significantly, which is attributed to less oxygen depletion via woodchip decomposition, which is common under wet conditions. Nitrate was significantly removed via denitrification in all three systems, indicating that the woodchip that occupied one-third of the main media was sufficient for denitrification, and also that the oxygen condition inside the column was proper for denitrification to proceed. A smaller amount of woodchip as the packing material also mitigated the adverse effect of the release of organics from the media during the initial period. In addition, the system showed very good buffering capacity, in that the outflow pH was constant within the optimal range for microorganism growth.
In this study it was demonstrated that when water hyacinth ponds (WHPs) are used for polishing the effluent from waste stabilization ponds (WSPs), suspended solids (mostly algal particles) are efficiently separated, which also resulted in the reduction of insoluble forms of COD and nutrients. The high pH of the WSPs effluent was easily adjusted to 6-7 as it passed through the WHPs. However, the use of water hyacinth rapidly reduced dissolved oxygen at the first cell to less than three mg/L or very frequently to a level of anaerobic state. Reduction of suspended solids at the WHPs mainly depends on the detention time and pH. An empirical separation model incorporating the detention time and pH dependence was developed.