The uneven electric field in cable accessory insulation can be optimized by field grading composite (FGC). We explored graphitic carbon nitride (g-C₃N₄) as a filler in liquid silicone rubber (LSR) matrices. Oxygen-doped g-C₃N₄ (O-g-C₃N₄) was prepared via calcination of g-C₃N₄ with ascorbic acid. Composites of g-C₃N₄/LSR and O-g-C₃N₄/LSR with different filler contents were fabricated. Microstructural and optical characterizations demonstrate that O-g-C₃N₄ retains the crystal structure of pristine g-C₃N₄ but exhibits thinner layers, modified elemental composition, and a 27.8% reduction in band gap; fillers are uniformly dispersed in the LSR matrix. Experimental measurements reveal that both composites exhibit nonlinear conductivity, while O-g-C₃N₄/LSR shows more pronounced nonlinearity at lower filler contents, accompanied by a faster decline in dielectric breakdown strength. There is little difference in thermal conductivity between g-C₃N₄/LSR and O-g-C₃N₄/LSR composites with the same filler content, which indicates that the change in band gap width has no significant influence on thermal conductivity. The low-cost synthesis and simple bandgap tuning method of g-C₃N₄ provide certain advantages for its use as a nonlinear filler in the preparation of FGC, broadening the application fields of g-C₃N₄, and verifying the possibility of reducing FGC filler usage through bandgap tuning.

Ammonia (NH₃) emissions during agricultural production can cause serious consequences on animal and human health, and it is quite vital to develop high-efficiency adsorbents for NH₃ removal from emission sources or air. Porous metal–organic frameworks (MOFs), as the most promising candidates for the capture of NH₃, offer a unique solid adsorbent design platform. In this work, a series of MOFs with different metal centers, ZnBTC, FeBTC and CuBTC, were proposed for NH₃ adsorption. The metal centers of the three MOFs are coordinated in a different manner and can be attacked by NH₃ with different strengths, resulting in different adsorption capacities of 11.33, 9.5, and 23.88 mmol/g, respectively. In addition, theoretical calculations, powder XRD patterns, FTIR, and BET for the three materials before and after absorption of ammonia were investigated to elucidate their distinctively different ammonia absorption mechanisms. Overall, the study will absolutely provide an important step in designing promising MOFs with appropriate central metals for the capture of NH₃.

Ammonia (NH₃) is a common pollutant mostly derived from pig manure composting under humid conditions, and it is absolutely necessary to develop materials for ammonia removal with high stability and efficiency. To this end, metal–organic frameworks (MOFs) have received special attention because of their high selectivity of harmful gases in the air, resulting from their large surface area and high density of active sites, which can be tailored by appropriate modifications. Herein, two synthetic metal–organic frameworks (MOFs), 2-methylimidazole zinc salt (ZIF-8) and zinc-trimesic acid (ZnBTC), were selected for ammonia removal under humid conditions during composting. The two MOFs, with different organic linkers, exhibit fairly distinctive ammonia absorption behaviors under the same conditions. For the ZnBTC framework, the ammonia intake is 11.37 mmol/g at 298 K, nine times higher than that of the ZIF-8 framework (1.26 mmol/g). In combination with theoretical calculations, powder XRD patterns, FTIR, and BET surface area tests were conducted to reveal the absorption mechanisms of ammonia for the two materials. The adsorption of ammonia on the ZnBTC framework can be attributed to both physical and chemical adsorption. A strong coordination interaction exists between the nitrogen atom from the ammonia molecule and the zinc atom in the ZnBTC framework. In contrast, the absorption of ammonia in the ZIF-8 framework is mainly physical. The weak interaction between the ammonia molecule and the ZIF-8 framework mainly results from the inherent severely steric hindrance, which is related to the coordination mode of the imidazole ligands and the zinc atom of this framework. Therefore, this study provides a method for designing promising MOFs with appropriate organic linkers for the selective capture of ammonia during manure composting.

With the rapid construction of new power systems characterized by high renewable energy penetration, high power electronics integration, and high voltage levels, the insulation reliability of critical power equipment—including cable accessories, gas-insulated switchgear (GIS), and power electronic modules—faces unprecedented challenges. Field grading materials (FGM), as core functional media for adaptive electric field homogenization and insulation failure prevention, have emerged as a research hotspot spanning materials science, electrical engineering, and polymer engineering. Starting from the current research status of FGM, this review systematically summarizes filler optimization strategies, covering single fillers, hybrid fillers, trace co-fillers, and structural modification approaches. The applications of FGM in transmission cables, GIS, high-voltage electrical machines, and wide-bandgap power electronic modules are then elaborated in detail. Emphasis is placed on performance enhancement routes of FGM, particularly thermal conductivity improvement via constructing three-dimensional thermally conductive networks and intelligent early warning based on thermochromic materials. Finally, the existing bottlenecks of FGM are analyzed in terms of material stability, multi-physical field coupling adaptation, and engineering industrialization. Future development trends are prospected toward high-performance, multifunctional, intelligent, and engineering-oriented FGM. This review aims to provide theoretical references and technical support for the design and application of advanced FGM in new power systems.