In the present work, promising proton conducting solid polymer blend electrolytes (SPBEs) composed of chitosan (CS) and methylcellulose (MC) were prepared for electrochemical double-layer capacitor (EDLC) application with a high specific capacitance and energy density. The change in intensity and the broad nature of the XRD pattern of doped samples compared to pure CS:MC system evidencedthe amorphous character of the electrolyte samples. The morphology of the samples in FESEM images supported the amorphous behavior of the solid electrolyte films. The results of impedance and Bode plotindicate that the bulk resistance decreasedwith increasing salt concentration. The highest DC conductivity was found to be 2.81 × 10⁻³ S/cm. The electrical equivalent circuit (EEC) model was conducted for selected samples to explain the complete picture of the electrical properties.The performance of EDLC cells was examined at room temperature by electrochemical techniques, such as impedance spectroscopy, cyclic voltammetry (CV) and constant current charge–discharge techniques. It was found that the studied samples exhibit a very good performance as electrolyte for EDLC applications. Ions were found to be the dominant charge carriers in the polymer electrolyte. The ion transference number (t_ion) was found to be 0.84 while 0.16 for electron transference number (t_el). Through investigation of linear sweep voltammetry (LSV), the CS:MC:NH₄SCN system was found to be electrochemically stable up to 1.8 V. The CV plot revealed no redox peak, indicating the occurrence of charge double-layer at the surface of activated carbon electrodes. Specific capacitance (C_spe) for the fabricated EDLC was calculated using CV plot and charge–discharge analyses. It was found to be 66.3 F g⁻¹ and 69.9 F g⁻¹ (at thefirst cycle), respectively. Equivalent series resistance (R_esr) of the EDLC was also identified, ranging from 50.0 to 150.0 Ω. Finally, energy density (E_d) was stabilized to anaverage of 8.63 Wh kg⁻¹ from the 10th cycle to the 100th cycle. The first cycle obtained power density (P_d) of 1666.6 W kg⁻¹ and then itdropped to 747.0 W kg⁻¹ at the 50th cycle and continued to drop to 555.5 W kg⁻¹ as the EDLC completed 100 cycles.

Solid polymer blend electrolyte membranes (SPBEM) composed of chitosan and dextran with the incorporation of various amounts of lithium perchlorate (LiClO₄) were synthesized. The complexation of the polymer blend electrolytes with the salt was examined using FTIR spectroscopy and X-ray diffraction (XRD). The morphology of the SPBEs was also investigated using field emission scanning electron microscopy (FESEM). The ion transport behavior of the membrane films was measured using impedance spectroscopy. The membrane with highest LiClO₄ content was found to exhibit the highest conductivity of 5.16 × 10⁻³ S/cm. Ionic (t_i) and electronic (t_e) transference numbers for the highest conducting electrolyte were found to be 0.98 and 0.02, respectively. Electrochemical stability was estimated from linear sweep voltammetry and found to be up to ~2.3V for the Li⁺ ion conducting electrolyte. The only existence of electrical double charging at the surface of electrodes was evidenced from the absence of peaks in cyclic voltammetry (CV) plot. The discharge slope was observed to be almost linear, confirming the capacitive behavior of the EDLC. The performance of synthesized EDLC was studied using CV and charge–discharge techniques. The highest specific capacitance was achieved to be 8.7 F·g⁻¹ at 20th cycle. The efficiency (η) was observed to be at 92.8% and remained constant at 92.0% up to 100 cycles. The EDLC was considered to have a reasonable electrode-electrolyte contact, in which η exceeds 90.0%. It was determined that equivalent series resistance (R_esr) is quite low and varies from 150 to 180 Ω over the 100 cycles. Energy density (E_d) was found to be 1.21 Wh·kg⁻¹ at the 1st cycle and then remained stable at 0.86 Wh·kg⁻¹ up to 100 cycles. The interesting observation is that the value of P_d increases back to 685 W·kg⁻¹ up to 80 cycles.

In the present work, chitosan (CS) as a natural biopolymer was used to prepare nanocomposite polymer electrolytes (NCPEs) in order to reduce plastic waste pollution. The plasticized CS-based NCSPE has been prepared via the solution casting technique. The electrical properties of the films were investigated using AC conductivity, dielectric properties, electric modulus, and electrical impedance spectroscopy (EIS). The obtained results from the dielectric properties and electric modulus study confirm the non-Debye behavior of ion dynamics. The effect of glycerol plasticizer on ionic conductivity of the CS:AgNO₃:Al₂O₃ system was investigated via AC conductivity and impedance studies. The conductivity of the samples was explained based on electrical equivalent circuits and Bode plots. The electrochemical properties such as transfer number measurement (TNM), linear sweep voltammetry (LSV), and cyclic voltammetry (CV) were carried out to inspect the sample suitability for electrochemical double-layer capacitor (EDLC) application. The highest conductivity was 3.7 × 10⁻⁴ S cm⁻¹ with the electrochemical stability window up to 2.1 V at room temperature. Through the TNM study, the ionic conductivity of plasticized CS-based NCSPE was confirmed, and ion transport (t_ion) of the highest conducting sample was found to be 0.985. The activated carbon electrode with the highest conducting sample was employed in the EDLC device fabrication. Accordingly, it can be said that the highest conducting sample had capable performance to be applied in electrochemical device application.