Toxic formaldehyde emissions, and the necessity to reduce the consumption of petrochemicals, stimulates the development of environmentally friendly adhesives. The aim of this research was to study, for the first time, the possibility of using condensed tannins (CTs)-rich extracts from grey alder (Alnus incana) and black alder (Alnus glutinosa) bark in the production of particleboards and plywood adhesives. The chemical structure, composition, and molecular weight of the CTs were identified by a 13C-NMR and TOF-MS analysis. Three innovative adhesive systems were studied: CTs-phenol-formaldehyde (CTs-PF) resin; a CTs-polyethyleneimine (PEI) adhesive system; and CTs–PEI combined with an ultra-low emitting formaldehyde resin (ULEFR)—CTs–PEI–ULEFR. The results showed that CTs-PF resin has properties close to commercial PF resin, and the formaldehyde emission was twice lower. CTs–PEI bonded particleboards corresponded to the requirements of the EN 312:2010 standard for particleboards in dry conditions (Type P2). CTs–PEI–ULEFR, with a 40–60% substitution of ULEFR by CTs–PEI, had adhesive properties very close to ULEFR; the plywood shear strength fit the requirements of the EN 314-2:1993 standard for application in internal and external system conditions. The introduction of extracted alder bark residues microparticles into the composition of the adhesive system showed their positive potential for application as a filler.
Different types of wood are used to manufacture of various wood products. In direct production processes, additional resources such as energy, adhesives, labor, etc. are also used. In line with sustainable environmental policies, all resources must be used more rationally, while simultaneously increasing the efficiency of the direct production processes. This research examined whether it is possible to reduce energy and labor resources in the technological process of hot pressing of birch plywood (nominal thickness 9 mm), by varying the holding time under pressure, pressure, and adhesive consumption. The Box-Behnken experimental design for a multifactor experiment was used to investigate the influence of technological parameters of plywood pressing. The highest strength in static bending both parallel and perpendicular to the plywood grain was achieved by pressing plywood with the following gluing parameters: highest pressing pressure, 3.2 MPa; minimal holding time under pressure, 9 minutes; and average phenol-formaldehyde adhesive consumption 150 grams per square meter.
In the market of the Latvia different wood surface coating materials suitable for use in outdoor conditions are offered, but available information on the efficiency of these against direct water exposure is insufficient. For structural timber building elements, such as glued laminated timber (GLT), the surface coating should be applied taking into account technological, visual or colour changes (ISO 7724:1984) and – last, but not least – economic aspects are considered. Wood surfaces coated with coating materials, such as varnishes, paints, etc. can stabilize some properties such as movement of moisture content, dimensional changes and attack by microorganisms and fungi. The changes in the moisture content of timber may influence such important parameters as mechanical properties and the total life time of the structural timber elements. A study has been conducted with the aim of assessing the efficiency of coating materials used for wood protection against water absorption. In this study, six different commercial coating products used for the treatment of spruce (Picea Abies L. Karst.) and pine (Pinus Sylvestris L.) samples were tested. The efficiency of different coating substances was assessed using two modified test methods according to the standards EN 382-2 (1994) and EN 927-5 (2006), determining the surface water absorption after immersion in water for 24 h and the dynamics of water absorption of the glued laminated timber for 696 h kept in water. As a result of the study, it has been ascertained that organic solvent-based commercial coating products are more efficient against short-term and long-term wood water absorption compared to oil-based coating materials.
It has been common knowledge that as the density of wood increases, the mechanical properties also improve. In turn, the density of wood depends on many factors, including the wood moisture content, location and cross-section in the trunk, the type of treatment and the parameters of technological processes. There is a great deal of research reported in the scientific literature on the effect of solid wood density on mechanical properties for different wood species as well as for structural timber. However, no research data can be found related investigation of the influence of veneer density on the properties of the birch plywood. In the present study, researching the properties of 7-ply birch plywood (thickness 9 mm), it was concluded that as the density of veneers increases, the bending properties of plywood in the direction of wood fibers (covered veneers) increases. When determining the plywood gluing quality, similar tendencies have been observed. For plywood with a lower density in all veneer plies the gluing quality (tensile-shear test) for perpendicular wood fiber veneers increases in the direction from the symmetry axis or middle veneer to the plywood outer plies, which can be explained by the fact that the outer plies become denser at the time of the hot pressing process. The results of the study will allow birch plywood manufacturers in direct production, sort veneers by density, to produce plywood with very predictable gluing quality, plywood thickness and mechanical properties in bending.
5 August 2015 in ENVIRONMENT. TECHNOLOGIES. RESOURCES. Proceedings of the International Scientific and Practical Conference
The bark of deciduous trees grown in Latvia: grey alder, black alder, ash tree and goat willow were sequentially extracted using solvents of increasing polarity. The data about total content of both lipophilic and hydrophilic compounds were obtained using sequentially extraction with hexane and ethanol. The highest yields of hydrophilic extractives were found for grey alder and ash tree barks (25.7% and 25.8%, respectively). Hydrophilic extract from the both alder species contained high amount (up to 12% on bark dry mass) of condensed tannins (CT) or oligomeric proanthocyanidins, whereas CT content of extract from ach tree was negligible. The main component of ethanol-water extract from alder bark was identified using 13C NMR and MALDI–TOF MS spectroscopy as a mixture of A- and B-type oligomeric procyanidins with the epicatechin units polymerization degree of 2-7. Ecologically friendly wood adhesives were obtained on the condensed tannin basis.
It is well known that wood tends to shrink and swell as the relative humidity of the air changes. There have been, and still are, attempts to make dimensionally stable wood panels such as Dendrolight®. The physical-mechanical, operational, including acoustic, properties of this material have been significantly improved compared to traditional wood-based panels. However, the production of this material requires very specific processing equipment and a large energy investment. The developers of this material in Latvia invented and patented wood, Lightweight Stabilised Blockboard (LSB). In order for this material to be used in the production of various products, it is necessary to clarify its characteristic, technological, as well as operational properties. The study gathers information about the sound absorption properties of various natural and wood materials, characteristics, and the sound absorption of the studied material at different sound frequencies. The reviewed sources of information indicate that nowadays there are still problems in sound conduction and absorption and isolation issues are being addressed in building acoustics. The production of samples and the determination of sound absorption were carried out using a developed methodology developed in accordance with regulatory requirements. The data obtained in the practical study were compared with the relevant indicators of the Dendrolight® and wood-based panels used for building structures and to determine their compliance with the requirements set forth in the standards ISO 10534-2 and ISO 11654. Research data show that LSB corresponds to E sound absorption class in some of the investigated frequencies.