Vertical wind shear (VWS) significantly impacts the vertical mixing of air pollutants and leads to changes in near-surface air pollutants. We focused on Changsha (CS) and Jingmen (JM), the upstream and downstream urban sites of a receptor region in central China, to explore the impact of VWS on surface PM_2.5 changes using 5-year wintertime observations and simulations from 2016–2020. The surface PM_2.5 concentration was lower in CS with higher anthropogenic PM_2.5 emissions than in JM, and the correlation between wind speed and PM_2.5 was negative for clean conditions and positive for polluted conditions in both two sites. The difference in the correlation pattern of surface PM_2.5 and VWS between CS and JM might be due to the different influences of regional PM_2.5 transport and boundary layer dynamics. In downstream CS, the weak wind and VWS in the height of 1–2 km stabilized the ABL under polluted conditions, and strong northerly wind accompanied by enhanced VWS above 2 km favored the long-range transport of air pollutants. In upstream JM, local circulation and long-range PM_2.5 transport co-determined the positive correlation between VWS and PM_2.5 concentrations. Prevailed northerly wind disrupted the local circulation and enhanced the surface PM_2.5 concentrations under polluted conditions, which tend to be an indicator of regional transport of air pollutants. The potential contribution source maps calculated from WRF-FLEXPART simulations also confirmed the more significant contribution of regional PM_2.5 transport to the PM_2.5 pollution in upstream region JM. By comparing the vertical profiles of meteorological parameters for typical transport- and local-type pollution days, the northerly wind prevailed throughout the ABL with stronger wind speed and VWS in transport-type pollution days, favoring the vertical mixing of transported air pollutants, in sharp contrast to the weak wind conditions in local-type pollution days. This study provided the evidence that PM_2.5 pollution in the Twain-Hu Basin was affected by long-distance transport with different features at upstream and downstream sites, improving the understanding of the air pollutant source–receptor relationship in air quality changes with regional transport of air pollutants.

The precipitation and raindrop size distribution (RSD) characteristics of the four seasons and different rain types were studied using a PARSIVEL² raindrop disdrometer set in the southwest mountain areas of China from 2019 to 2021. The seasonal precipitation in the southwest mountain areas was mainly stratiform rain. The peaks of the RSD were about 1–2 orders of magnitude higher than those in the plains. The convective rain in spring and autumn was very close to the ocean-like convective mass. The local shape–slope (μ–Λ), radar reflectivity–rain rate (Z–R), and kinetic energy–rain rate (KE–R) relationships were further derived, and the diversity of these relationships was mainly due to the variability of the RSDs. In addition, the differences in the RSD characteristics between the top and the foot of the mountain during a typical precipitation process in the summer of 2020 were further compared. It was found that the number density of the small particles at the top of the mountain was higher than that at the foot of the mountain due to the broken large raindrops caused by the high wind speed, while the high evaporation rate, strong convective available potential energy (CPAE), and water vapor content at the foot of the mountain could strengthen the RSD, making the number density of the large raindrops at the foot of the mountain higher than that at the top.

The impact of structural variations in the atmospheric boundary layer (ABL) during the regional transport of air pollutants on its local pollution changes deserves attention. Based on multi-source ABL detection and numerical simulation of air pollutants over the Twain-Hu Basin (THB) during 4–6 January 2019, the mechanism of the rapid growth of atmospheric pollutant concentrations in Xianning by the synergistic effect of regional transport and ABL evolution is explored, and the main conclusions are obtained as follows. The vertically stratified atmosphere is noticeable at nighttime, and the heavy humidity of near-surface fog within the stable boundary layer (SBL) promoted the generation and cumulative growth of secondary PM_2.5 components during the pollution formation stage. The horizontal transport characteristics of atmospheric pollutant concentration peak were observed in the residual layer (RL) of 500–600 m. At the pollution maintenance stage, the convective boundary layer (CBL) developed during the daytime, and northerly wind transported high-concentration pollutants from the north to the THB. Under the combined action of horizontal transport and turbulent mixing, the high-concentration atmospheric pollutants in the mixing layer (ML) from the ground to the 500 m height were mixed uniformly and maintained accumulation growth. The next day, the strong vertical turbulent mixing caused the downward transport of high-concentration pollutants in the RL during nighttime due to the development of the CBL again, resulting in a doubling of near-surface pollutant concentration in a short time. With the development of ABL turbulence, local pollution dissipated rapidly without the continuous input of pollutants from external regions. This study emphasizes the importance of multi-scale processes impact on pollution variation, that is, regional transport of atmospheric pollutants at the CBL development stage for the rapid growth of PM_2.5 concentration in the ML.

The influence of the underlying surface on the atmospheric environment over rivers and lakes is not fully understood. To improve our understanding, this study targeted the Twain-Hu Basin (THB) in central China, with a unique underlying surface comprising a dense “water network” over rivers and lakes. In this study, the Weather Research and Forecasting Model with Chemistry (WRF-Chem) was used to simulate the impact of this dense “water network” on a wintertime heavy PM_2.5 pollution event in the THB. On this basis, the regulating effects of density and area of the lake groups, with centralized big lakes (CBLs) and discrete small lakes (DSLs), on PM_2.5 concentrations over the underlying surface of the dense “water network” in the THB were clarified, and the relative contributions of thermal factors and water vapor factors in the atmospheric boundary layer to the variation of PM_2.5 concentrations were evaluated. The results show that the underlying surface of dense “water networks” in the THB generally decreases the PM_2.5 concentrations, but the influences of different lake-group types are not uniform in spatial distribution. The CBLs can reduce the PM_2.5 concentrations over the lake and its surroundings by 4.90–17.68% during the day and night. The ability of DSLs in reducing PM_2.5 pollution is relatively weak, with the reversed contribution between −5.63% and 1.56%. Thermal factors and water vapor–related factors are the key meteorological drivers affecting the variation of PM_2.5 concentrations over the underlying surface of dense “water networks”. The warming and humidification effects of such underlying surfaces contribute positively and negatively to the “purification” of air pollution, respectively. The relative contributions of thermal factors and water vapor–related factors are 52.48% and 43.91% for CBLs and 65.96% and 27.31% for DSLs, respectively. The “purification” effect of the underlying surface with a dense “water network” in the THB on regional air pollution highlights the importance of environmental protection of inland rivers and lakes in regional environmental governance. In further studies on the atmospheric environment, long-term studies are necessary, including fine measurements in terms of meteorology and the environment and more comprehensive simulations under different scenarios.