Nikolai Denkov

Prof. Dr. Nikolai Denkov

Laboratory of Active Formulations and Materials, Department of Chemical and Pharmaceutical Engineering, Faculty of Chemistry and Pharmacy, Sofia University, Sofia, Bulgaria
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Research Focus & Metrics

Academic Career Length

37Years (1990-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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1 December 1992 in Langmuir
Verified
Journal Article
Closed access
Nikolai DenkovNikolai Denkov
Nikolai Denkov
OVOrlin Velev
Orlin Velev
PKP. Kralchevski
P. Kralchevski
III. Ivanov
I. Ivanov
HYH. Yoshimura
H. Yoshimura
KNK. Nagayama
K. Nagayama

1 January 1996 in Langmuir
Verified
Journal Article
Closed access
Krastanka MarinovaKrastanka Marinova
Krastanka Marinova
RAR. G. Alargova
R. G. Alargova
Nikolai DenkovNikolai Denkov
Nikolai Denkov
OVOrlin Velev
Orlin Velev
DPD. N. Petsev
D. N. Petsev
RBR. P. Borwankar
R. P. Borwankar

7 January 1993 in Nature
Verified
Journal Article
Closed access
Nikolai DenkovNikolai Denkov
Nikolai Denkov
OVO. D. Velev
O. D. Velev
PKPeter Kralchevsky
Peter Kralchevsky
III. B. Ivanov
I. B. Ivanov
HYH. Yoshimura
H. Yoshimura
KNK. Nagayama
K. Nagayama

1 August 2001 in Current Opinion in Colloid & Interface Science
Verified
Journal Article
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PKPeter Kralchevsky
Peter Kralchevsky
Nikolai DenkovNikolai Denkov
Nikolai Denkov

4 February 2008 in Physical Chemistry Chemical Physics
Verified
Journal Article
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STS. Tcholakova
S. Tcholakova
Nikolai DenkovNikolai Denkov
Nikolai Denkov
ALA. Lips
A. Lips
The aim of this paper is to present a short overview of the main mechanisms operative in the formation and stabilization of emulsions by solid particles and, on this basis, to make comparisons between solid particles, surfactants and globular proteins as emulsifiers. When available, simple quantitative relations are presented, with the respective numerical estimates and discussion of the applicability of these relations to particle-stabilized systems. Non-obvious similarities between the different types of emulsifiers are outlined in several cases in which the description of the system can be performed at a phenomenological level. Examples are presented for the process of emulsification, where we show that several simple theoretical expressions, derived originally in the studies of surfactants and protein emulsifiers, can be successfully applied to particle-stabilized emulsions. In contrast, for the phenomena in which the detailed mechanisms of particle adsorption and film stabilization are important, the differences between the various emulsifiers prevail, thus making it impossible to use the same theoretical description. The most important specific characteristics of the solid particles which strongly affect their behavior are the high barrier to particle adsorption, high desorption energy and strong capillary forces between particles trapped in liquid films, which all originate in the relatively large particle size (as compared to the size of surfactant and protein molecules). The capillary mechanism of stabilization of liquid films by solid particles is reviewed in some detail, to emphasize its specific features and to demonstrate the applicability of several simple expressions for approximate estimates. Interestingly, we found that the hypothesis for some exceptionally high coalescence stability of the particle-stabilized emulsions is not supported by the experimental data available in literature. On the other hand, the particles are able to completely arrest the process of Ostwald ripening in foams and emulsions, and this effect can be easily explained with the high desorption energy of the particles and the resulting capillary effects.

24 June 2004 in Langmuir
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Journal Article
Closed access
Nikolai DenkovNikolai Denkov
Nikolai Denkov