Knowledge of the dynamic changes in the water absorption process of heat-treated wood is important for providing a scientific basis for the reasonable application of heat-treated wood, especially for outdoor applications. Nuclear magnetic resonance (NMR) techniques provide detailed information about the moisture components and moisture transport processes in wood, which are not available with other methods. In this work, water absorption of untreated and heat treated Chinese fir (Cunninghamia lanceolata [Lamb.] Hook.) heartwood was investigated using various NMR methods. The heat treatment temperatures were varied between 160 °C and 220 °C. According to the spin-spin relaxation time (T2), there were two components of water in the samples heat-treated at 160 °C and 180 °C as well as the untreated sample, while three components of water were found in the samples heat-treated at 200 °C and 220 °C, and the mass of each component was calculated by the integral peak areas of the T2 curve. The amount of bound water and free water in heat-treated samples were less compared to the untreated ones, and the water absorption decreased correspondingly, due to the increasing heat-treated temperature. The results obtained by one dimensional frequency coding indicated that the heat treatment made wood difficult to be accessed by moisture. Besides, NMR images revealed that the free water absorption in latewood was faster than in earlywood, but earlywood could absorb more water than latewood.
The time dependency of the orthotropic compliance for Chinese fir wood [Cunninghamia lanceolata (Lamb.) Hook] has been investigated by performing compressive creep experiments in all orthotropic directions. Time evolution of the creep strain in the axial and lateral directions was recorded by means of the digital image correlation (DIC) technique, to determine the diagonal and nondiagonal elements of the viscoelastic compliance matrix. The results reveal the significant influence of time on the mechanical behavior. The orthotropic nature of the viscoelastic compliance is highlighted by the different time dependency of the Young’s moduli and the Poisson’s ratios obtained for the individual directions. Differences among the time-dependent stress-strain relationship determined at the 25, 50, and 75% stress levels indicate that the viscoelastic behavior of wood is also load-dependent. A Poisson’s ratio values, which are increasing with time in νLR, νLT, νRT, νTR, and decreasing in νRL and νTL, demonstrate that the creep strain is influenced by loading directions. The substantially different time dependency of the nondiagonal elements of the compliance matrix further reveals the orthotropic compliance asymmetry and emphasizes the complexity of the viscoelastic character of wood.