Porous FeCrN stainless steel has excellent corrosion resistance, biocompatibility and mechanical properties matching human bone because of non-nickel and manganese, which is a new direction of medical implants. In this paper, FeCrN stainless steel with porosity of 28.21%-60.16% was prepared by powder metallurgy method. The microstructure, pore morphology and mechanical properties of porous stainless steel were analyzed by means of XRD, SEM, EDS and compression test. The microstructure of porous stainless steel is mostly austenite + ferrite. With the increase of porosity, the compressive yield strength, compressive strength and elastic modulus of the material decrease.

This work explores the impact of hydrogen reduction on sintering and nitriding of porous high-nitrogen austenitic stainless steel (HNASS) processed via powder metallurgy. A temperature-resolved hydrogen reduction (temperature range of 700–1250 °C) was performed to evaluate the phase composition of porous HNASS. The systematic microstructure was characterized by a scanning electron microscope (SEM) with energy disperse spectroscopy (EDS), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The compressive mechanical properties and electrochemical corrosion behavior of the unreduced and reduced samples were discussed. Samples reduced in hydrogen at 1100 °C and 1250 °C show better compressive properties while still retaining good corrosion resistance. Reduction of oxide facilitates sintering thus improves the compressive properties. Increasing the content of solute nitrogen and reducing the precipitation of nitride can effectively improve the corrosion resistance of porous HNASS.

High-nitrogen stainless steel (HNSS) has been widely concerned and studied owing to its excellent mechanical, corrosion resistance, and biocompatibility properties. A series of HNSS was prepared by metal injection molding (MIM) using gas atomized Fe–Cr–Mn–Mo–0.3 N duplex stainless steel powders. Both sintering and solution treatments were carried out in an N₂ atmosphere. The effects of nitrogen distribution and phase transformation on the mechanical properties of MIM HNSS during sintering and solution were studied. The results show that as the sintering temperature increased, the sample density increased, but the total nitrogen content decreased. Nitrogen and Cr₂N concentration gradients along the cross-section of as-sintered samples were formed after cooling. The high nitrogen content promotes the decomposition of γ: γ_saturated translated to γ and Cr₂N. Meanwhile, the low Mn content in austenite also decomposes γ: γ translated to α and Cr₂N. After solution treatment, a single γ phase was obtained for samples sintered at 1200 to 1320 °C. For solution treatment samples sintered at 1320 and 1350 °C, their tensile strength was 988.76 and 1036.12 MPa; yield strength was 615.61 and 636.14 MPa, and elongation was 42.58 and 40.08%, respectively. These values vastly exceeded the published MIM HNSS values.

Powder metallurgy is widely used to fabricate high-nitrogen, nickel-free austenitic stainless steel. However, after sintering and nitriding, additional solution treatment is typically required to achieve uniform nitrogen distribution and a homogeneous austenite phase. This work proposes a novel method to eliminate the need for lengthy and high-temperature solution treatment by switching the nitrogen atmosphere to argon during the cooling process. The effects of different N₂-Ar atmosphere-switching temperatures (750–1320 °C) on the phase composition, element distribution, microstructure, mechanical properties, and corrosion resistance of the studied steels were systematically investigated. Results show that cooling in the N₂ atmosphere initially transforms the matrix to a fully austenitic structure enriched with nitrogen. Excessive nitrogen infiltration leads to Cr₂N precipitation, inducing partial austenite decomposition and forming a multiphase structure comprising austenite, α-Fe, and Cr₂N. Strategic switching from N₂ to Ar reverses this reaction, yielding a high-nitrogen, chemically uniform austenitic structure. Specifically, switching at 1150 °C, the steel exhibits excellent mechanical properties and corrosion resistance, with a yield strength of 749 MPa, an ultimate tensile strength of 1030 MPa, an elongation of 38.7%, and a corrosion current of 0.06 mA/cm², outperforming the steels cooled solely in N₂ and subsequently solution-treated. This novel method offers advantages in cost reduction, energy saving, and operational effectiveness, highlighting its potential for broad industrial application.