The corrosive water environment has a decisive influence on the durability of a diversion tunnel lining. In this paper, the effects of carbonation on cement-based materials in water-immersion and saturated-humidity environments were studied by increasing the CO₂ concentration. The results show that under conditions of water-immersion and saturated humidity, the color of the non-carbonation region is dark, while the carbonation region is gray, and the color boundary is obvious. However, in an atmospheric environment, there is no zone with a dark color and the color boundary is not obvious. In a saturated-humidity environment, the carbonation depth increases over time and changes greatly, and its value is about 16.71 mm at 200 days. While in a water-immersion environment, the carbonation depth varies little with time and the value is only 2.31 mm. The carbonation depths of cement mortar samples in different environments generally follow a linear relationship with the square root of time. The carbonation coefficient in a saturated-humidity environment is more than nine times that in the water-immersion environment. In a water-immersion environment, the carbonation causes a large loss of calcium in cement-based materials, and their Ca/Si ratio obviously decreases. The calcium silicon ratio (Ca/Si) of cement-based materials in a water-immersion environment is 0.11, which is much less than 1.51 in a water-saturated environment and 1.49 in an atmospheric environment. In a saturated-humidity environment, the carbonation only reduces the pH of the pore solution in the carbonation region, and the structural stability of cement-based materials is not degraded. The number of pores of all radii after carbonation in a water-immersion environment exceeds that in a saturated-humidity environment, and the total pore volume and average pore radius in a water-immersion environment are also larger than in a saturated-humidity environment, so the water-immersion environment accelerates the development and expansion of pores. The research results can provide some theoretical and technical support for the design, construction, and safe operation of diversion tunnel linings.

The swelling-shrinkage and cracking characteristics of compacted clay under the coupling effect of initial conditions are rarely studied. The dry-wet cycle test of compacted clay with varying initial water contents and densities was performed in this study; the size and cracking conditions were investigated. The results showed that when the initial moisture content was 21% and the dry density was 1.65 g/cm³, the longitudinal expansion amount of the compacted clay was relatively small. However, it was rather large when the initial water content was 17% and 19%. Under the same dry density, the final vertical shrinkage ratio of the sample with a water content of 21% was the smallest, while that of the samples with a water content of 23% and 25% was rather big. Under the same water content, the final vertical shrinkage ratio decreased with the increase in dry density. After three wetting-drying cycles, compacted clay with a dry density of 1.65 g/cm³ and an optimal initial water content of 21% produced the fewest cracks and had the lowest cracking factor (CF) (only 7.58%). The compacted clay specimens with the dry densities of 1.55 g/cm³ and 1.60 g/cm³ had rather significant cracking at the same initial moisture content of 21%. The mercury intrusion porosimetry (MIP) test demonstrated that in the first two dry and wet cycles, the distribution of large pores decreased and that of tiny pores increased. After the third cycle, the distribution of small and medium pores decreased slightly. The results of this study will provide theoretical guidance for selecting cover soils in landfills.

Solidification/stabilization (S/S) is one of the most widely used techniques in the disposal of heavy-metal-contaminated soil, though the long-term effectiveness of S/S technology remains implicit. Temperature is an important factor affecting the leaching behavior of heavy metals and the long-term effectiveness of S/S treatment. This study systematically explored the influence of temperature on the leaching behavior of lead in an S/S monolith through semi-dynamic leaching test at different temperatures. The results showed that an increase in temperature could accelerate the leaching concentration and cumulative leaching amount of lead ions in the S/S monolith. The cumulative leaching amount of lead ions in the S/S monolith after 11 days at 55 °C was about 5.8 times that at 25 °C. The leaching rate of lead ions in the S/S monolith increased with the increase in temperature. The leaching index of lead ions was larger than 9, which met the requirements for “controlled utilization” in the environment. The leaching mechanism of lead ions was diffusion control and did not change in the temperature range of 25–55 °C. These findings indicate that temperature affects the leaching behavior and the long-term effectiveness of S/S treatment, and temperature variation should be considered in the effectiveness evaluation of S/S treatment.