Compared with the deeply buried marine gas hydrate deposits, gas hydrates in the shallow subsurface, close to and at the seafloor, have attracted more attention owing to their concentrated distribution, high saturation, and easy access. They accumulate at relatively shallow depths <100–120 m and occur as gas hydrate-bearing mounds (also known as hydrate outcrops, pingoes) at the seafloor derived from the growth of hydrates in the shallow subsurface or as pure hydrate chunks formed by gas leakage. This paper reviews and summarizes such gas hydrate systems globally from the perspective of gas sources, migration pathways, and accumulation processes. Here, we divided them into four categories: fault-chimney-controlled, diapir-fault-controlled, fault-controlled, and submarine mud volcano-controlled deposits. Gas chimneys originate immediately above the restricted regions, mostly affected by faults where high gas concentrations trigger elevated pore fluid pressures. Diapirism derives a dendritic network of growth faults facilitating focused gas discharge and hydrate formation near the seafloor. Furthermore, pre-existing faults or fractures created by overpressured gas from greater depths in accretionary tectonics at convergent margins act as preferential pathways channeling free gas upwards to the seafloor. Gas flux rates decrease from the submarine mud volcano center to its margins, creating a concentric pattern of distributing temperature, gas concentrations, and hydrate contents in shallow sediments around the mud volcano. Hydrate-bound hydrocarbons are commonly of thermogenic origin and correspond to high-background geothermal conditions, whereas microbial gas is dominant in a few cases. The presence of heavier hydrocarbons mitigates the inhibition of hydrate formation by salt or heat. Fluid migration and pathways could be compared to the “blood” and “bones” in an organic system, respectively. The root of a pathway serves as the “heart” that gathers and provides considerable free gas concentrations in a restricted area, thereby triggering pore fluid pressures as one important drive force for focused fluid flow in impermeable sediments (the organic system). Besides the suitable temperature and pressure conditions, a prerequisite for the formation and stability of hydrate deposits in the shallow subsurface and at the seafloor is the sufficient supply of gas-rich fluids through the hydrate stability zone. Thus, the proportion of gas migrating from deep sources is significantly larger than that trapped in hydrates. As such, such marine hydrate deposits seem more like temporary carbon storage rather than the main culprit for climate warming at least in a short period.

The Sturtian (720–670 Ma) glacial–interglacial transition period was an important interval for sedimentary manganese metallogenesis, including the Mn oxide deposit in the Otjosondu region in Namibia and Mn carbonate deposits in the Datangpo Formation in the south-eastern Yangtze Platform, South China. During this period, Earth experienced the breakup of Rodinia, the Sturtian glaciation, and the Neoproterozoic oxygenation event. In this study, we investigate scenarios that might have provided geologically and geochemically favorable conditions for Mn metallogenesis. In these scenarios, the global recovery of microorganisms enhanced marine primary productivity and O₂ levels of the hydrosphere and atmosphere during the Sturtian glacial–interglacial transition. However, the water column was not completely oxidized, maintaining redox stratification. Transgression–regression cycles or O₂-rich downwelling drove the exchange of oxygenated topwater and anoxic deep water in rift-related basins that developed due to Rodinia’s breakup. The coupling of these processes precipitated existing dissolved Mn(II) at the margins of basins (Otjosondu region) or at their centers (Yangtze Platform). In the latter case, precursor Mn oxides were further converted into Mn carbonates via the reduction of Mn oxides coupled with organic matter oxidation during early diagenesis. A brief review of Mn metallogenesis in the geological record reveals that Mn metallogenic processes typically occur under geo-environmental conditions that, in concert, produce favorable conditions for Mn sourcing, concentration, and sedimentation.