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Rainfall-runoff events significantly influence water runoff and the loss of pollutants from tile-drained agricultural land. We monitored ten small (4 to 38 ha) tile-drained catchments in Czechia for three to five years (2012 to 2016). The discharge was measured continuously; a regular 14-day scheme of water quality monitoring was accompanied with event sampling provided by automatic samplers in 20 to 120 min intervals. A new semi-automated algorithm was developed for the identification of runoff events (RE) based on discharge and water temperature changes. We then quantified the share of RE on the total runoff and the N and P losses, and we compared six methods for nutrient load estimation on an annual and monthly basis. The results showed considerable differences among the monitored sites, seasons, and applied methods. The share of RE on N loads was on average 5% to 30% of the total annual load, whereas for P (dissolved and total), the share of RE was on average 10% to 80% on the total annual load. The most precise method for nutrient load estimation included the RE. The methods based on point monitoring of the discharge and water quality underestimated the loads of N by 10% to 20% and of P by 30% to 80%. The acquired findings are crucial for the improvement of nutrient load assessment in tile-drained catchments, as well as for the design of various mitigation measures on tile-drained agricultural land.

Dynamics of pesticides and their metabolites in drainage waters during baseflow periods and rainfall-runoff events (RREs) were studied from 2014 to 2016 at three small, tile-drained agricultural catchments in Bohemian-Moravian Highlands, Czech Republic. Drainage systems in this region are typically built in slopes with considerable proportion of drainage runoff originating outside the drained area itself. Continuous monitoring was performed by automated samplers, and the event hydrograph was separated using ¹⁸O and ²H isotopes and using drainage water temperature. Results showed that drainage systems represent a significant source for pesticides leaching from agricultural land. Leaching of pesticide metabolites was mainly associated with baseflow and shallow interflow. Water from causal precipitation diluted their concentrations. The prerequisite for the leaching of parental compounds was a rainfall-runoff event occurring shortly after spraying, and the presence of event water in the runoff. When such situations happened consequently, pesticides concentrations in drainage water were high and the pesticide load reached several grams in a few hours. Presented results introduce new insights in the processes of pesticides movement in small, tile-drained catchments and emphasizes the need to incorporate drainage hydrology and flow-triggered sampling into monitoring programmes in larger catchments as well as in environment-conservation policy.

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