As the first invention to efficiently harvest electricity from ambient mechanical energy by using contact electrification, the triboelectric nanogenerator has elicited worldwide attention because of its cost-effectiveness and sustainability. This study exploits a superhydrophobic nanostructured aluminum tube to estimate electrical output for solid-water contact electrification inside a tubular system. The linearly proportional relationship of short-circuit current and open-circuit voltage to the detaching speed of water was determined by using a theoretical energy harvesting model and experimentation. A pioneering stick-type solid-water interacting triboelectric nanogenerator, called a SWING stick, was developed to harvest mechanical energy through solid-water contact electrification generated when the device is shaken by hand. The electrical output generated by various kinds of water from the environment was also measured to demonstrate the concept of the SWING stick as a compact triboelectric nanogenerator. Several SWING sticks were connected to show the feasibility of the device as a portable and compact source of direct power. The developed energy harvesting model and the SWING stick can provide a guideline for the design parameters to attain a desired electrical output; therefore, this study can significantly increase the applicability of a water-driven triboelectric nanogenerator.
The triboelectric series is a generally accepted method for describing the triboelectric effect. It provides a way to control the double face of the ubiquitous triboelectric effect: causes of unpredictable accidents and the resultant surface charge as energy sources. However, previous studies have been biased in solids despite being observed in liquids (liquid‐solid contact electrification). Therefore, a liquid triboelectric series is necessary to be established to manipulate the liquid triboelectric effect according to the appropriate goal. In this study, a liquid triboelectric series is first established to describe the triboelectric properties of each liquid when contact electrification occurs with a solid surface. The liquid triboelectric series covers electrolytes, organic solvents, oxidants, and higher sugar alcohols. Common chemical groups can be derived from the liquid triboelectric series that hydroxyl groups enhance, and benzene groups suppress the liquid triboelectric effect. The results are demonstrated by the amplified efficiency of an energy harvester and particle contamination after surface washing. This study will play a pivotal role in understanding the liquid‐solid contact electrification phenomenon and providing new perspectives on the applications of the liquid triboelectric effect.