Supercapacitors (SCs) have generated a great deal of interest regarding their prospects for application in energy storage due to their advantages such as long life cycles and high-power density. Graphene is an excellent electrode material for SCs due to its high electric conductivity and highly specific surface area. Conductive polymers (CPs) could potentially become the next-generation SC electrodes because of their low cost, facile synthesis methods, and high pseudocapacitance. Graphene/CP composites show conspicuous electrochemical performance when used as electrode materials for SCs. In this article, we present and summarize the synthesis and electrochemical performance of graphene/CP composites for SCs. Additionally, the method for synthesizing electrode materials for better electrochemical performance is discussed.

Flotation is one of the most used methods to upgrade natural graphite resources. However, the efficiency is usually decreased due to the entrainment of undesirable fine gangue minerals. In this work, the impact of different factors such as particle size, pulp density, and flotation reagent on the entrainment of mica and quartz in a flake graphite flotation was studied. The single gangue mineral flotation results showed increased gangue entrainment when reducing the particle size of gangue minerals and increasing the pulp density. Moreover, the flotation of artificial mixtures indicated enhanced entrainment of mica and quartz in the presence of graphite particles. The collector and frother also strongly affect gangue entrainment by modifying the structure and stability of the froth. Kerosene, which has a prominent deforming feature, can reduce gangue entrainment more effectively than diesel.

As the high value and the scarcity of large-flake graphite ore resources, it is in the best interest to maximize the amount of large flakes and minimize any processing that will reduce flake sizes. In the study, the mineralogy of an African graphite ore was estimated using X-ray diffraction (XRD), X-ray fluorescence (XRF), and optical microscope analyses. The results indicated that it was a heavily weathered large flake graphite ore and the main gangue minerals were quartz and kaolinite. The graphite flakes were thick, bent, and fractured, and some clay minerals were embedded into the graphite interlayer, which made it difficult to prevent the large flakes from being destroyed using mechanical grinding methods. An approach of steel rod coarse grinding and pebble regrinding effectively reduced the destruction of graphite flakes and improved the grinding efficiency. In addition, comparing with the conventional process, a pre-screening process was applied and the content of large flakes in the final concentrate was significantly improved.

Inorganic electrolytes are assumed to significantly impact the flotation performance of graphite resources; however, the underlying mechanism is still unclear. In this work, the effect of three inorganic salts, including KCl, MgCl₂, and AlCl₃, was studied on the flotation of graphite. Flotation results indicated significantly increased graphite recovery with the addition of KCl regardless of pulp pH. MgCl₂ improved the flotation performance under acidic and slightly alkaline conditions, while AlCl₃ had a better activation on graphite flotation under strong acidic and alkaline conditions. Contact angle and Zeta potential results confirmed that electrolytes substantially reduced the absolute value of surface charge and the hydration of graphite surface, thus improving the hydrophobicity. Froth stability studies indicated that multivalent Al³⁺ and Mg²⁺ ions exhibit superior foaming performance than K⁺ ions and contribute to more stable and abundant foam. Additionally, these salt ions increased the surface tension and prevented bubble coalescence, contributing to nanobubble formation. Therefore, adding MgCl₂ and KCl is of great significance for improved graphite flotation under neutral conditions.

Natural graphite ores are usually upgraded by froth flotation. However, complex processes with multistage grinding and flotation are required to achieve decent liberation and separation of graphite and gangue minerals. This study reports a short and improved flotation process for fine flake graphite ore by employing a thickening stage. The results indicated that increasing the regrinding concentration via thickening can improve the grinding efficiency and, thus, shorten the separation process. With thickening, a high-grade intermediate concentrate of 96.01% was obtained after three steps of cleaner flotation, which is close to the final concentrate after five steps. Particle size distribution analysis and FIB-SEM-EDS studies suggested that the main contribution of thickening–regrinding was to achieve better abrasion rather than attrition of the graphite flakes, thus liberating the interlayer impurities without reducing the size of the graphite flakes. This study offers a more cost-effective pathway for the simplified flotation of natural graphite ores.