The widespread use of proton exchange membrane water electrolysis requires the development of more efficient electrocatalysts containing reduced amounts of expensive iridium for the oxygen evolution reaction (OER). Here we present the identification of 6H-phase SrIrO3 perovskite (6H-SrIrO3) as a highly active electrocatalyst with good structural and catalytic stability for OER in acid. 6H-SrIrO3 contains 27.1 wt% less iridium than IrO2, but its iridium mass activity is about 7 times higher than IrO2, a benchmark electrocatalyst for the acidic OER. 6H-SrIrO3 is the most active catalytic material for OER among the iridium-based oxides reported recently, based on its highest iridium mass activity. Theoretical calculations indicate that the existence of face-sharing octahedral dimers is mainly responsible for the superior activity of 6H-SrIrO3 thanks to the weakened surface Ir-O binding that facilitates the potential-determining step involved in the OER (i.e., O* + H2O → HOO* + H+ + e¯).
13 July 2017 in Journal of the American Chemical Society
Cotton gauze is a widely used topical hemostatic material for bleeding control, but its high blood absorption capacity tends to cause extra blood loss. Therefore, development of rapid hemostatic cotton gauze with less blood loss is of great significance. Here, we develop an efficient hemostatic cotton gauze whose surface is slightly modified with a catechol compound which features a flexible long hydrophobic alkyl chain terminated with a catechol group. Its hemostatic performance in animal injuries is superior to standard cotton gauze and Combat GauzeTM. Its biosafety is similar to cotton gauze and rebleeding hardly occurs when the gauze is removed. Here, we show its hemostatic capability is attributable to the rapid formation of big and thick primary erythrocyte clots, due to its effective controlling of blood movement through blocking effect from tissue adhesion by catechol, blood wicking in cotton, and the hydrophobic effect from long alkyl chains.
Ultra-thin N-doped-graphene encapsulated Ni nanoparticles coupled with MoO2 nanosheets are prepared for HER and OER. As used for overall water splitting, it can work for 196 h at 1000 mA cm−2.
22 September 2021 in ACS Applied Materials & Interfaces