Helical nanomaterials represent an emerging group of nanostructures with unique spiral geometry as well as multiple functionalities owing to their enriched physical and chemical properties. With the novel properties enabled by their nanoscale dimension and unique geometry, the helical nanostructures may open opportunities to develop our understanding of new physics, chemistry and biology, and enable new nanodevice design and fabrication. This review article presents a comprehensive and in-depth overview of the latest progress in helical nanostructures synthesis, properties and potential applications. Specific attention is concentrated on the crystal growth theory for helical nanostructures, summary of the helical nanomaterials obtained so far, and their fabrication techniques as well as typical physical properties that can be potentially utilized for various applications.

Supported metal single atom catalysts (SACs) present an emerging class of low-temperature catalysts with high reactivity and selectivity, which, however, face challenges on both durability and practicality. Herein, we report a single-atom Pt catalyst that is strongly anchored on a robust nanowire forest of mesoporous rutile titania grown on the channeled walls of full-size cordierite honeycombs. This Pt SAC exhibits remarkable activity for oxidation of CO and hydrocarbons with 90% conversion at temperatures as low as ~160 ^oC under simulated diesel exhaust conditions while using 5 times less Pt-group metals than a commercial oxidation catalyst. Such an excellent low-temperature performance is sustained over hydrothermal aging and sulfation as a result of highly dispersed and isolated active single Pt ions bonded at the Ti vacancy sites with 5 or 6 oxygen ions on titania nanowire surfaces.